TY - JOUR
T1 - Vapor-liquid equilibria of binary and ternary systems containing carbon dioxide, alkane, and benzothiophene
AU - Camacho-Camacho, Luis E.
AU - Galicia-Luna, Luis A.
AU - Elizalde-Solis, Octavio
PY - 2011/11/10
Y1 - 2011/11/10
N2 - Experimental vapor-liquid equilibrium (VLE) data of binary and ternary systems are reported covering all of the phase envelopes up to near the critical point. The carbon dioxide + dodecane, carbon dioxide + benzothiophene, and carbon dioxide + nonane + benzothiophene systems were studied at (318.14, 344.75, 373.23, and 417.91) K, 373.93 K, and (313.09, 343.73, and 373.74) K, respectively. The apparatus is based on the static-analytic method with an on-line ROLSI (rapid on-line sampler-injector) sampler to allow fast determination of the VLE. Standard uncertainties for the measured properties in this work were estimated to be p ± 0.01 MPa, T ± 0.03 K, liquid mole fraction xCO2 ± 0.0036, and vapor mole fraction y CO2 ± 0.0016. The experimental VLE data for carbon dioxide + dodecane were found to be in agreement with those available in the literature at 318 K. Furthermore, the corresponding results for the ternary system indicate a high selectivity of nonane in the vapor phase instead of benzothiophene. Data obtained in this work were correlated with the Peng-Robinson equation of state using the Wong-Sandler mixing rules.
AB - Experimental vapor-liquid equilibrium (VLE) data of binary and ternary systems are reported covering all of the phase envelopes up to near the critical point. The carbon dioxide + dodecane, carbon dioxide + benzothiophene, and carbon dioxide + nonane + benzothiophene systems were studied at (318.14, 344.75, 373.23, and 417.91) K, 373.93 K, and (313.09, 343.73, and 373.74) K, respectively. The apparatus is based on the static-analytic method with an on-line ROLSI (rapid on-line sampler-injector) sampler to allow fast determination of the VLE. Standard uncertainties for the measured properties in this work were estimated to be p ± 0.01 MPa, T ± 0.03 K, liquid mole fraction xCO2 ± 0.0036, and vapor mole fraction y CO2 ± 0.0016. The experimental VLE data for carbon dioxide + dodecane were found to be in agreement with those available in the literature at 318 K. Furthermore, the corresponding results for the ternary system indicate a high selectivity of nonane in the vapor phase instead of benzothiophene. Data obtained in this work were correlated with the Peng-Robinson equation of state using the Wong-Sandler mixing rules.
UR - http://www.scopus.com/inward/record.url?scp=80955149614&partnerID=8YFLogxK
U2 - 10.1021/je200586g
DO - 10.1021/je200586g
M3 - Artículo
SN - 0021-9568
VL - 56
SP - 4109
EP - 4115
JO - Journal of Chemical and Engineering Data
JF - Journal of Chemical and Engineering Data
IS - 11
ER -