Tribochemical Synthesis and Study of Mixed Potassium-Ferrous Ferrocyanide and its RuII and OsII Analogs

E. Reguera; J. Fernández-Bertrán; L. Nuñez

doi:10.1515/znb-1995-0714

Tribochemical Synthesis and Study of Mixed Potassium-Ferrous Ferrocyanide and its Ru^II and Os^II Analogs

E. Reguera, J. Fernández-Bertrán, L. Nuñez

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Mixed potassium-ferrous ferrocyanide and its Ru^II and Os^II analogs have been synthesized tribochemically by grinding Fe(SO₄).7H₂O with the equivalent amount of K₄[Fe(CN)₆]–3H₂O and the Ru^II and Os^II compounds. Their XRD powder patterns and Mossbauer and IR spectra were recorded and interpreted. The role of hydration water on the feasibility of the tribochemical synthesis is discussed.

Original language	English
Pages (from-to)	1067-1070
Number of pages	4
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	50
Issue number	7
DOIs	https://doi.org/10.1515/znb-1995-0714
State	Published - 7 Jan 1995
Externally published	Yes

Keywords

Ferrocyanide
IR Spectra
Mössbauer Spectra

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abstract = "Mixed potassium-ferrous ferrocyanide and its RuII and OsII analogs have been synthesized tribochemically by grinding Fe(SO4).7H2O with the equivalent amount of K4[Fe(CN)6]–3H2O and the RuII and OsII compounds. Their XRD powder patterns and Mossbauer and IR spectra were recorded and interpreted. The role of hydration water on the feasibility of the tribochemical synthesis is discussed.",

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year = "1995",

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T1 - Tribochemical Synthesis and Study of Mixed Potassium-Ferrous Ferrocyanide and its RuII and OsII Analogs

AU - Reguera, E.

AU - Fernández-Bertrán, J.

AU - Nuñez, L.

PY - 1995/1/7

Y1 - 1995/1/7

N2 - Mixed potassium-ferrous ferrocyanide and its RuII and OsII analogs have been synthesized tribochemically by grinding Fe(SO4).7H2O with the equivalent amount of K4[Fe(CN)6]–3H2O and the RuII and OsII compounds. Their XRD powder patterns and Mossbauer and IR spectra were recorded and interpreted. The role of hydration water on the feasibility of the tribochemical synthesis is discussed.

AB - Mixed potassium-ferrous ferrocyanide and its RuII and OsII analogs have been synthesized tribochemically by grinding Fe(SO4).7H2O with the equivalent amount of K4[Fe(CN)6]–3H2O and the RuII and OsII compounds. Their XRD powder patterns and Mossbauer and IR spectra were recorded and interpreted. The role of hydration water on the feasibility of the tribochemical synthesis is discussed.

KW - Ferrocyanide

KW - IR Spectra

KW - Mössbauer Spectra

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U2 - 10.1515/znb-1995-0714

DO - 10.1515/znb-1995-0714

M3 - Artículo

SN - 0932-0776

VL - 50

SP - 1067

EP - 1070

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 7

ER -

Tribochemical Synthesis and Study of Mixed Potassium-Ferrous Ferrocyanide and its Ru^II and Os^II Analogs

Abstract

Keywords

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