TY - JOUR
T1 - Trans-chlorido(4-fluorobenzenethiolato-κS)bis(triphenylphosphane- κP)palladium(II) methanol hemisolvate
AU - Avila-Sorrosa, Alcives
AU - Santacruz-Juárez, Ericka
AU - Reyes-Arellano, Alicia
AU - Reyes-Martínez, Reyna
AU - Morales-Morales, David
PY - 2014/3
Y1 - 2014/3
N2 - The title compound, [Pd(SC6H4F-p)Cl(PPh 3)2]·0.5CH3OH, features a Pd II complex with two triphenylphosphane (PPh3) ligands arranged in a trans conformation, with one chloride and one 4-fluorobenzenethiolate ligand completing the coordination sphere, giving rise to a slightly distorted square-planar geometry of the PdII ion. The methanol solvent molecule is disordered about an inversion centre with an occupancy of 0.25 for each molecule. In the crystal, weak C - H⋯Cl hydrogen-bonding interactions between the complex molecules generate chain frameworks parallel to [010].
AB - The title compound, [Pd(SC6H4F-p)Cl(PPh 3)2]·0.5CH3OH, features a Pd II complex with two triphenylphosphane (PPh3) ligands arranged in a trans conformation, with one chloride and one 4-fluorobenzenethiolate ligand completing the coordination sphere, giving rise to a slightly distorted square-planar geometry of the PdII ion. The methanol solvent molecule is disordered about an inversion centre with an occupancy of 0.25 for each molecule. In the crystal, weak C - H⋯Cl hydrogen-bonding interactions between the complex molecules generate chain frameworks parallel to [010].
KW - Data-to-parameter ratio = 14.8
KW - Disorder in solvent or counterion
KW - Mean σ(C-C) = 0.007 Å
KW - R factor = 0.043
KW - Single-crystal X-ray study
KW - T = 298 K
KW - wR factor = 0.110
UR - http://www.scopus.com/inward/record.url?scp=84897678564&partnerID=8YFLogxK
U2 - 10.1107/S1600536814002499
DO - 10.1107/S1600536814002499
M3 - Artículo
C2 - 24764953
SN - 1600-5368
VL - 70
SP - m92-m93
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 3
ER -