TY - JOUR
T1 - Trans-Bis(μ-benzenethiolato-κ2 S:S) bis[chlorido(triphenylphosphane-κP)palladium(II)] chloroform disolvate
AU - Avila-Sorrosa, Alcives
AU - Reyes-Arellano, Alicia
AU - Germán-Acacio, Juan Manuel
AU - Reyes-Martínez, Reyna
AU - Morales-Morales, David
PY - 2013/8
Y1 - 2013/8
N2 - The title compound, [Pd2Cl2(C6H5S)2(C18H15P)2]·2CHCl3, contains a centrosymmetric dinuclear palladium complex with the PdII cation in a slightly distorted square-planar coordination environment. The PdII cations are bridged by the S atoms of two benzenethiolate ligands with different Pd - S distances [2.2970 (11) and 2.3676 (11) Å]. The coordination of the metal atom is completed by a chloride anion [2.3383 (11) Å] and a triphenylphosphane ligand [2.2787 (11) Å]. Weak C - H⋯Cl interactions are present between complex molecules and the CHCl3 solvent molecule. The latter is disordered over two positions in a 0.792 (8):0.208 (8) ratio. The crystal under investigation was found to be twinned by nonmerohedry, with a fraction of 73.4 (1)% for the major twin component.
AB - The title compound, [Pd2Cl2(C6H5S)2(C18H15P)2]·2CHCl3, contains a centrosymmetric dinuclear palladium complex with the PdII cation in a slightly distorted square-planar coordination environment. The PdII cations are bridged by the S atoms of two benzenethiolate ligands with different Pd - S distances [2.2970 (11) and 2.3676 (11) Å]. The coordination of the metal atom is completed by a chloride anion [2.3383 (11) Å] and a triphenylphosphane ligand [2.2787 (11) Å]. Weak C - H⋯Cl interactions are present between complex molecules and the CHCl3 solvent molecule. The latter is disordered over two positions in a 0.792 (8):0.208 (8) ratio. The crystal under investigation was found to be twinned by nonmerohedry, with a fraction of 73.4 (1)% for the major twin component.
KW - Rfactor = 0.039
KW - T = 298 K
KW - data-toparameter ratio = 15.3
KW - disorder in solvent or counterion
KW - meanω(C - C) = 0.009 A °
KW - single-crystal X-ray study
KW - wRfactor = 0.088
UR - http://www.scopus.com/inward/record.url?scp=84881456554&partnerID=8YFLogxK
U2 - 10.1107/S1600536813019806
DO - 10.1107/S1600536813019806
M3 - Artículo
C2 - 24109288
SN - 1600-5368
VL - 69
SP - m472
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 8
ER -