TY - JOUR
T1 - Thermal properties of centrifuged oils measured by alternative photothermal techniques
AU - Carbajal-Valdez, R.
AU - Jiménez-Pérez, J. L.
AU - Cruz-Orea, A.
AU - Correa-Pacheco, Z. N.
AU - Alvarado-Noguez, M. L.
AU - Romero-Ibarra, I. C.
AU - Mendoza-Alvarez, J. G.
N1 - Publisher Copyright:
© 2017 Elsevier B.V.
PY - 2017/11/10
Y1 - 2017/11/10
N2 - In this work, thermal characterization of centrifuged aromatic citrus oils was studied using thermal lens (TL) and open photoacoustic cell (OPC). The thermal diffusivity (D) was obtained by TL, fitting the critical time parameter of the experimental curves to the theoretical values. An experimental arrangement of non-matched mode lasers with a probe and an excitation lasers was used. On the other hand, the thermal effusivity (e) of the samples was obtained by using OPC. The thermal conductivity (k) was calculated from the relationship between D and e. The thermal parameters obtained were compared with theoretical values in the literature. UV–vis spectroscopy, Attenuated Total Reflectance-Fourier Transform Infrared spectroscopy (ATR-FTIR) and 1H Nuclear Magnetic Resonance (NMR) were used to determine the absorption coefficients and chemical structure of the citrus oils. The importance of this research work was the determination of the thermal parameters of essential oils as an alternative technique for quality control application.
AB - In this work, thermal characterization of centrifuged aromatic citrus oils was studied using thermal lens (TL) and open photoacoustic cell (OPC). The thermal diffusivity (D) was obtained by TL, fitting the critical time parameter of the experimental curves to the theoretical values. An experimental arrangement of non-matched mode lasers with a probe and an excitation lasers was used. On the other hand, the thermal effusivity (e) of the samples was obtained by using OPC. The thermal conductivity (k) was calculated from the relationship between D and e. The thermal parameters obtained were compared with theoretical values in the literature. UV–vis spectroscopy, Attenuated Total Reflectance-Fourier Transform Infrared spectroscopy (ATR-FTIR) and 1H Nuclear Magnetic Resonance (NMR) were used to determine the absorption coefficients and chemical structure of the citrus oils. The importance of this research work was the determination of the thermal parameters of essential oils as an alternative technique for quality control application.
KW - Citrus essential oils
KW - Open photoacoustic cell
KW - Thermal diffusivity
KW - Thermal effusivity
KW - Thermal lens
UR - http://www.scopus.com/inward/record.url?scp=85029807057&partnerID=8YFLogxK
U2 - 10.1016/j.tca.2017.09.014
DO - 10.1016/j.tca.2017.09.014
M3 - Artículo
AN - SCOPUS:85029807057
SN - 0040-6031
VL - 657
SP - 66
EP - 71
JO - Thermochimica Acta
JF - Thermochimica Acta
ER -