The CN stretch of insoluble metal nitroprussides as a sensor of ligand-outer cation interactions

J. Fernández-Bertrán; E. Reguera

doi:10.1080/00387019508009441

The CN stretch of insoluble metal nitroprussides as a sensor of ligand-outer cation interactions

J. Fernández-Bertrán, E. Reguera

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3 Scopus citations

Abstract

The CN frequencies of insoluble metal nitroprussides are correlated with the atomic parameters of the outer cations. The results indicate that the nature of the interaction is predominantly of the cr donor-acceptor type with no relevant it back-donation from the outer cations to the CN ligand.

Original language	English
Pages (from-to)	1015-1020
Number of pages	6
Journal	Spectroscopy Letters
Volume	28
Issue number	7
DOIs	https://doi.org/10.1080/00387019508009441
State	Published - 1 Oct 1995
Externally published	Yes

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title = "The CN stretch of insoluble metal nitroprussides as a sensor of ligand-outer cation interactions",

abstract = "The CN frequencies of insoluble metal nitroprussides are correlated with the atomic parameters of the outer cations. The results indicate that the nature of the interaction is predominantly of the cr donor-acceptor type with no relevant it back-donation from the outer cations to the CN ligand.",

author = "J. Fern{\'a}ndez-Bertr{\'a}n and E. Reguera",

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AU - Reguera, E.

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N2 - The CN frequencies of insoluble metal nitroprussides are correlated with the atomic parameters of the outer cations. The results indicate that the nature of the interaction is predominantly of the cr donor-acceptor type with no relevant it back-donation from the outer cations to the CN ligand.

AB - The CN frequencies of insoluble metal nitroprussides are correlated with the atomic parameters of the outer cations. The results indicate that the nature of the interaction is predominantly of the cr donor-acceptor type with no relevant it back-donation from the outer cations to the CN ligand.

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DO - 10.1080/00387019508009441

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The CN stretch of insoluble metal nitroprussides as a sensor of ligand-outer cation interactions

Abstract

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