The CN stretch of hexacyanometallates as a sensor of ligand-outer cation interactions-I. Ferricyanides and cobalticyanides

José Fernández Bertrán; José Blanco Pascual; Edilso Reguera Ruiz

doi:10.1016/0584-8539(90)80023-R

The CN stretch of hexacyanometallates as a sensor of ligand-outer cation interactions-I. Ferricyanides and cobalticyanides

José Fernández Bertrán, José Blanco Pascual, Edilso Reguera Ruiz

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Abstract

The CN frequencies of 39 hexacyanometallates (ferricyanides and cobalticyanides) are correlated with atomic parameters of the outer cation. Evidence is obtained of the presence of σ and π interactions in the bonding of the outer cation to the CN ligand. Quantitative estimation of the effect of these mechanisms on the shift of ν_CN is presented.

Original language	English
Pages (from-to)	685-689
Number of pages	5
Journal	Spectrochimica Acta Part A: Molecular Spectroscopy
Volume	46
Issue number	5
DOIs	https://doi.org/10.1016/0584-8539(90)80023-R
State	Published - 1990
Externally published	Yes

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10.1016/0584-8539(90)80023-R

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title = "The CN stretch of hexacyanometallates as a sensor of ligand-outer cation interactions-I. Ferricyanides and cobalticyanides",

abstract = "The CN frequencies of 39 hexacyanometallates (ferricyanides and cobalticyanides) are correlated with atomic parameters of the outer cation. Evidence is obtained of the presence of σ and π interactions in the bonding of the outer cation to the CN ligand. Quantitative estimation of the effect of these mechanisms on the shift of νCN is presented.",

author = "Bertr{\'a}n, {Jos{\'e} Fern{\'a}ndez} and Pascual, {Jos{\'e} Blanco} and Ruiz, {Edilso Reguera}",

year = "1990",

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journal = "Spectrochimica Acta Part A: Molecular Spectroscopy",

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T1 - The CN stretch of hexacyanometallates as a sensor of ligand-outer cation interactions-I. Ferricyanides and cobalticyanides

AU - Bertrán, José Fernández

AU - Pascual, José Blanco

AU - Ruiz, Edilso Reguera

PY - 1990

Y1 - 1990

N2 - The CN frequencies of 39 hexacyanometallates (ferricyanides and cobalticyanides) are correlated with atomic parameters of the outer cation. Evidence is obtained of the presence of σ and π interactions in the bonding of the outer cation to the CN ligand. Quantitative estimation of the effect of these mechanisms on the shift of νCN is presented.

AB - The CN frequencies of 39 hexacyanometallates (ferricyanides and cobalticyanides) are correlated with atomic parameters of the outer cation. Evidence is obtained of the presence of σ and π interactions in the bonding of the outer cation to the CN ligand. Quantitative estimation of the effect of these mechanisms on the shift of νCN is presented.

UR - http://www.scopus.com/inward/record.url?scp=4243728769&partnerID=8YFLogxK

U2 - 10.1016/0584-8539(90)80023-R

DO - 10.1016/0584-8539(90)80023-R

M3 - Artículo

SN - 0584-8539

VL - 46

SP - 685

EP - 689

JO - Spectrochimica Acta Part A: Molecular Spectroscopy

JF - Spectrochimica Acta Part A: Molecular Spectroscopy

IS - 5

ER -

The CN stretch of hexacyanometallates as a sensor of ligand-outer cation interactions-I. Ferricyanides and cobalticyanides

Abstract

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