TY - JOUR
T1 - Synthesis of ZnO/ PrO2 + Pr(OH)3 nanoparticles for solar photodegradation of anionic and cationic mixed dyes
AU - Ovando-Medina, Víctor M.
AU - Villabona-Leal, E. G.
AU - Antonio-Carmona, Iveth D.
AU - Martínez-Gutiérrez, Hugo
AU - Romero-Galarza, Adolfo
AU - Dector, A.
AU - Mendoza-León, Hector F.
AU - Olivares-Ramírez, Juan Manuel
N1 - Publisher Copyright:
© 2023, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.
PY - 2023/4
Y1 - 2023/4
N2 - A composite of ZnO and Pr (3% mol of Pr/Zn) was synthesized in one-step using ZnCl2 and PrCl3 as precursors and NaOH to precipitate the oxides, resulting in a composite of ZnO/PrO2 + Pr(OH)3. Composite of ZnO/PrO2 + Pr(OH)3 was characterized by scanning electron microscopy, thermogravimetric analysis, UV/Vis–NIR spectroscopy and X-ray diffraction. Composite consisted of micro-rods of 5 to 10 µm in length coated with agglomerated nanoparticles of PrO2 + Pr(OH)3. From the UV/Vis–NIR spectrum, the calculated band-gap energy values of composite were 3.05 and 2.73 eV for direct and indirect transitions, respectively. In addition, the characteristic f–f transitions of the Pr3+ ions were also identified due to photoactivity in both: the UV and visible regions of the electromagnetic spectrum. ZnO/PrO2 + Pr(OH)3 composite was tested in photodegradation of methylene blue (MB) and reactive red 120 (RR-120) dyes under solar irradiation (1.15 ± 0.15 W/m2) and 1 g/L of photocatalyst load. It was observed that for a MB dye solution 30 mg/L of initial concentration, 81% of photodegradation was achieved after 120 min of solar irradiation, this efficiency increased to 97% for initial MB dye concentration of 10 mg/L in 90 min. The photodegradation efficiency for RR-120 was 98% at 10 mg/L of RR-120 initial concentration in only 45 min, however in the competitive photodegradation of the mixed dyes at 20 mg/L of initial concentration, 99% and 95% of efficiency were achieved for MB and RR-120 after 120 min, respectively. The photocatalytic activity of composite was associated with two mechanisms: (1) light absorption in the UV/Vis region activating the CTB band (charge transfer band, O2− → Zn2+, Pr3+) and the f–f bands of the Pr3+ ions. (2) The presence of the redox-pair Pr4+ + e− → P3+ (ε0 = 3.2 V) that would capture the photogenerated e−CB. Both mechanisms increase the lifetime of the exciton.
AB - A composite of ZnO and Pr (3% mol of Pr/Zn) was synthesized in one-step using ZnCl2 and PrCl3 as precursors and NaOH to precipitate the oxides, resulting in a composite of ZnO/PrO2 + Pr(OH)3. Composite of ZnO/PrO2 + Pr(OH)3 was characterized by scanning electron microscopy, thermogravimetric analysis, UV/Vis–NIR spectroscopy and X-ray diffraction. Composite consisted of micro-rods of 5 to 10 µm in length coated with agglomerated nanoparticles of PrO2 + Pr(OH)3. From the UV/Vis–NIR spectrum, the calculated band-gap energy values of composite were 3.05 and 2.73 eV for direct and indirect transitions, respectively. In addition, the characteristic f–f transitions of the Pr3+ ions were also identified due to photoactivity in both: the UV and visible regions of the electromagnetic spectrum. ZnO/PrO2 + Pr(OH)3 composite was tested in photodegradation of methylene blue (MB) and reactive red 120 (RR-120) dyes under solar irradiation (1.15 ± 0.15 W/m2) and 1 g/L of photocatalyst load. It was observed that for a MB dye solution 30 mg/L of initial concentration, 81% of photodegradation was achieved after 120 min of solar irradiation, this efficiency increased to 97% for initial MB dye concentration of 10 mg/L in 90 min. The photodegradation efficiency for RR-120 was 98% at 10 mg/L of RR-120 initial concentration in only 45 min, however in the competitive photodegradation of the mixed dyes at 20 mg/L of initial concentration, 99% and 95% of efficiency were achieved for MB and RR-120 after 120 min, respectively. The photocatalytic activity of composite was associated with two mechanisms: (1) light absorption in the UV/Vis region activating the CTB band (charge transfer band, O2− → Zn2+, Pr3+) and the f–f bands of the Pr3+ ions. (2) The presence of the redox-pair Pr4+ + e− → P3+ (ε0 = 3.2 V) that would capture the photogenerated e−CB. Both mechanisms increase the lifetime of the exciton.
UR - http://www.scopus.com/inward/record.url?scp=85154027458&partnerID=8YFLogxK
U2 - 10.1007/s10854-023-10424-8
DO - 10.1007/s10854-023-10424-8
M3 - Artículo
AN - SCOPUS:85154027458
SN - 0957-4522
VL - 34
JO - Journal of Materials Science: Materials in Electronics
JF - Journal of Materials Science: Materials in Electronics
IS - 12
M1 - 1004
ER -