TY - JOUR
T1 - Synthesis of PAMAM dendrimers with porphyrin core and functionalized periphery as templates of metal composite materials and their toxicity evaluation
AU - Hernández Ramírez, Raquel E.
AU - Lijanova, Irina V.
AU - Likhanova, Natalya V.
AU - Olivares Xometl, Octavio
AU - Hernández Herrera, Alfredo
AU - Federico Chávez Alcalá, J.
AU - Trejo Chavero, Octavio
N1 - Publisher Copyright:
© 2017 The Authors
PY - 2020/1
Y1 - 2020/1
N2 - Experiments were performed for the synthesis of meso-substituted tetraphenyl porphyrins in order to obtain growth active points for PAMAM branches and a functionalized periphery with thiazole groups for increasing the metal complexation activity. Characterization by 1H and 13C NMR, mass spectrometry and infrared spectrometry confirmed the produced dendrimeric nanostructures; the chemical reduction of metallic Ag and Cu inside the dendrimer was proved by XPS. Finally, the toxicity of the metal-dendrimer complex was analyzed by means of the bacterial respiration test.
AB - Experiments were performed for the synthesis of meso-substituted tetraphenyl porphyrins in order to obtain growth active points for PAMAM branches and a functionalized periphery with thiazole groups for increasing the metal complexation activity. Characterization by 1H and 13C NMR, mass spectrometry and infrared spectrometry confirmed the produced dendrimeric nanostructures; the chemical reduction of metallic Ag and Cu inside the dendrimer was proved by XPS. Finally, the toxicity of the metal-dendrimer complex was analyzed by means of the bacterial respiration test.
KW - Metal complex
KW - Metal species
KW - PAMAM-dendrimers
KW - Porphyrin
UR - http://www.scopus.com/inward/record.url?scp=85012277812&partnerID=8YFLogxK
U2 - 10.1016/j.arabjc.2017.01.013
DO - 10.1016/j.arabjc.2017.01.013
M3 - Artículo
AN - SCOPUS:85012277812
SN - 1878-5352
VL - 13
SP - 27
EP - 36
JO - Arabian Journal of Chemistry
JF - Arabian Journal of Chemistry
IS - 1
ER -