TY - JOUR
T1 - Synthesis of hectorite-TiO2 and kaolinite-TiO2 nanocomposites with photocatalytic activity for the degradation of model air pollutants
AU - Kibanova, Daria
AU - Trejo, Martin
AU - Destaillats, Hugo
AU - Cervini-Silva, Javiera
N1 - Funding Information:
DK thanks the support of a DGAPA-UNAM scholarship. The authors express gratitude to P. Fernandez and P. Santiago-Jacinto (UNAM) for technical support, to R. Hernadez-Reyes (UNAM, SEM), to D. Lucas and A.T. Hodgson (LBNL-EETD), to B. Gilbert (LBNL-ESD) for XRD data acquisition and interpretation, to M. Salmeron and V. Altoe (LBNL-MSD, XPS), to J.T. Larsen (LBNL-ESD, ICP-OES) and to V. Battaglia and X. Song (LBNL-EETD, BET analysis). This project was supported in part by UNAM [Proyecto Universitario de Nanotecnología Ambiental (PUNTA), DGAPA-UNAM, PAPIIT (Grant No. IN116007-2)], the Mexican Academy of Sciences (Academia Mexicana de Ciencias) and the United States–Mexico Foundation for Science (Fundación México–Estados Unidos para la Ciencia) through the 2006-Young Researcher Summer Program Fellowship (AMC-FUMEC), CONACYT [SEP-CONACYT Ciencia Básica 2006, Grant no. 61670], the UC MEXUS Program and by LBNL (LDRD Project # 366088).
PY - 2009/1
Y1 - 2009/1
N2 - We studied the synthesis and photocatalytic activity of small-sized TiO2 supported on hectorite and kaolinite. Deposition of TiO2 on the clay mineral surface was conducted by using a sol-gel method with titanium isopropoxide as precursor. Anatase TiO2 particles formation was achieved by hydrothermal treatment at 180 °C. Material characterization was conducted using XRD, SEM, XPS, ICP-OES, BET and porosimetry analysis. fficiency in synthesizing clay-TiO2 composites depended strongly on the clay mineral structure. Incorporation of anatase in hectorite, an expandable clay mineral, was found to be very significant (> 36 wt.% Ti) and to be followed by important structural changes at the clay mineral surface. Instead, no major structural modifications of the clay were observed for kaolinite-TiO2, as compared with the untreated material. Photocatalytic performance of clay-TiO2 composites was evaluated with ATR-FTIR following the oxidation of adsorbed toluene and d-limonene, two model air pollutants. In either case, the photocatalytic removal efficiency of these hydrophobic substrates by the synthesized clay-TiO2 composites was comparable to that observed using pure commercial TiO2 (Degussa P25).
AB - We studied the synthesis and photocatalytic activity of small-sized TiO2 supported on hectorite and kaolinite. Deposition of TiO2 on the clay mineral surface was conducted by using a sol-gel method with titanium isopropoxide as precursor. Anatase TiO2 particles formation was achieved by hydrothermal treatment at 180 °C. Material characterization was conducted using XRD, SEM, XPS, ICP-OES, BET and porosimetry analysis. fficiency in synthesizing clay-TiO2 composites depended strongly on the clay mineral structure. Incorporation of anatase in hectorite, an expandable clay mineral, was found to be very significant (> 36 wt.% Ti) and to be followed by important structural changes at the clay mineral surface. Instead, no major structural modifications of the clay were observed for kaolinite-TiO2, as compared with the untreated material. Photocatalytic performance of clay-TiO2 composites was evaluated with ATR-FTIR following the oxidation of adsorbed toluene and d-limonene, two model air pollutants. In either case, the photocatalytic removal efficiency of these hydrophobic substrates by the synthesized clay-TiO2 composites was comparable to that observed using pure commercial TiO2 (Degussa P25).
KW - Clays
KW - Hectorite
KW - Indoor pollutants
KW - Kaolinite
KW - Photocatalysis
KW - Titania
KW - Toluene
KW - VOCs
KW - d-limonene
UR - http://www.scopus.com/inward/record.url?scp=56549095278&partnerID=8YFLogxK
U2 - 10.1016/j.clay.2008.03.009
DO - 10.1016/j.clay.2008.03.009
M3 - Artículo
SN - 0169-1317
VL - 42
SP - 563
EP - 568
JO - Applied Clay Science
JF - Applied Clay Science
IS - 3-4
ER -