Abstract
Titania-magnesia mixed oxides, with magnesia concentrations between 10 and 90 wt%, were prepared by using the sol-gel method with titanium n-butoxide and magnesium ethoxide as precursors. The mixed oxides were characterized with X-ray powder diffraction, BET nitrogen adsorption isotherms, electron spin resonance (ESR), and by testing their catalytic activity for 2-propanol and 2-butanol dehydration. Samples contained periclase, anatase, karooite (MgTi2O5), geikielite (MgTiO3), and qandilite (Mg2TiO4). The BET specific surface area varied with magnesia concentration; the samples with 50 wt% MgO had the highest area, 211 m2/g. Samples had paramagnetic centers that produced complex ESR spectra when many crystalline phases coexisted. For 2-propanol and 2-butanol decomposition, the activity and selectivity patterns of the mixed oxides were substantially different to those observed in pure TiO2 and pure MgO. This singular behavior should be a result of the structural defects created by the substitution of Mg2+ ions by Ti4+ cations in titania lattice, as well as by the interfaces created when several crystalline phases coexisted.
Original language | English |
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Pages (from-to) | 5689-5693 |
Number of pages | 5 |
Journal | Langmuir |
Volume | 15 |
Issue number | 18 |
DOIs | |
State | Published - 1 Jan 1999 |