Study of the lithium insertion and de-insertion in perovskite praseodymium bismuth lithium titanate

Mario Fidel García; Nestor Fernández; Katia Borrego; María Luisa Martínez-Sarrión; Lourdes Mestres; Marta Herraiz

doi:10.1016/j.jeurceramsoc.2004.01.019

Study of the lithium insertion and de-insertion in perovskite praseodymium bismuth lithium titanate

Mario Fidel García, Nestor Fernández, Katia Borrego, María Luisa Martínez-Sarrión, Lourdes Mestres, Marta Herraiz

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The stoichiometry and lithium-insertion reactions with n BuLi in solid solutions Pr_0.5+x-yLi_0.5-3xBi_y TiO₃ have been studied. The results indicate that bismuth affects these processes. Two joins with bismuth and lithium constant, respectively, are studied in the phase diagram. The amount of lithium inserted depends on the number of vacancies and the amount of bismuth in the original sample. The amount of lithium de-inserted depends only on the amount of bismuth. The cell volume increases when the amount of the lithium inserted increases, but anomalous dependence is observed in de-insertion. The presence of bismuth decreases the amount of lithium inserted in the sample, but favors the reversibility of the insertion.

Original language	English
Pages (from-to)	729-734
Number of pages	6
Journal	Journal of the European Ceramic Society
Volume	25
Issue number	5
DOIs	https://doi.org/10.1016/j.jeurceramsoc.2004.01.019
State	Published - Feb 2005
Externally published	Yes

Keywords

(Pr,Li,Bi)TiO
Insertion reactions
Intercalation
Perovskites

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10.1016/j.jeurceramsoc.2004.01.019

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title = "Study of the lithium insertion and de-insertion in perovskite praseodymium bismuth lithium titanate",

abstract = "The stoichiometry and lithium-insertion reactions with n BuLi in solid solutions Pr0.5+x-yLi0.5-3xBiy TiO3 have been studied. The results indicate that bismuth affects these processes. Two joins with bismuth and lithium constant, respectively, are studied in the phase diagram. The amount of lithium inserted depends on the number of vacancies and the amount of bismuth in the original sample. The amount of lithium de-inserted depends only on the amount of bismuth. The cell volume increases when the amount of the lithium inserted increases, but anomalous dependence is observed in de-insertion. The presence of bismuth decreases the amount of lithium inserted in the sample, but favors the reversibility of the insertion.",

keywords = "(Pr,Li,Bi)TiO, Insertion reactions, Intercalation, Perovskites",

author = "Garc{\'i}a, {Mario Fidel} and Nestor Fern{\'a}ndez and Katia Borrego and Mart{\'i}nez-Sarri{\'o}n, {Mar{\'i}a Luisa} and Lourdes Mestres and Marta Herraiz",

note = "Funding Information: This work studied was sponsored by the Ministerio de Ciencia y Tecnolog{\'ı}a, Proyecto BQU2002-00619, Generalitat de Catalunya, Proyecto 2001SGR00052, and by a Universitat de Barcelona grant.",

year = "2005",

month = feb,

doi = "10.1016/j.jeurceramsoc.2004.01.019",

language = "Ingl{\'e}s",

volume = "25",

pages = "729--734",

journal = "Journal of the European Ceramic Society",

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TY - JOUR

T1 - Study of the lithium insertion and de-insertion in perovskite praseodymium bismuth lithium titanate

AU - García, Mario Fidel

AU - Fernández, Nestor

AU - Borrego, Katia

AU - Martínez-Sarrión, María Luisa

AU - Mestres, Lourdes

AU - Herraiz, Marta

N1 - Funding Information: This work studied was sponsored by the Ministerio de Ciencia y Tecnologı́a, Proyecto BQU2002-00619, Generalitat de Catalunya, Proyecto 2001SGR00052, and by a Universitat de Barcelona grant.

PY - 2005/2

Y1 - 2005/2

N2 - The stoichiometry and lithium-insertion reactions with n BuLi in solid solutions Pr0.5+x-yLi0.5-3xBiy TiO3 have been studied. The results indicate that bismuth affects these processes. Two joins with bismuth and lithium constant, respectively, are studied in the phase diagram. The amount of lithium inserted depends on the number of vacancies and the amount of bismuth in the original sample. The amount of lithium de-inserted depends only on the amount of bismuth. The cell volume increases when the amount of the lithium inserted increases, but anomalous dependence is observed in de-insertion. The presence of bismuth decreases the amount of lithium inserted in the sample, but favors the reversibility of the insertion.

AB - The stoichiometry and lithium-insertion reactions with n BuLi in solid solutions Pr0.5+x-yLi0.5-3xBiy TiO3 have been studied. The results indicate that bismuth affects these processes. Two joins with bismuth and lithium constant, respectively, are studied in the phase diagram. The amount of lithium inserted depends on the number of vacancies and the amount of bismuth in the original sample. The amount of lithium de-inserted depends only on the amount of bismuth. The cell volume increases when the amount of the lithium inserted increases, but anomalous dependence is observed in de-insertion. The presence of bismuth decreases the amount of lithium inserted in the sample, but favors the reversibility of the insertion.

KW - (Pr,Li,Bi)TiO

KW - Insertion reactions

KW - Intercalation

KW - Perovskites

UR - http://www.scopus.com/inward/record.url?scp=12744261769&partnerID=8YFLogxK

U2 - 10.1016/j.jeurceramsoc.2004.01.019

DO - 10.1016/j.jeurceramsoc.2004.01.019

M3 - Artículo

AN - SCOPUS:12744261769

SN - 0955-2219

VL - 25

SP - 729

EP - 734

JO - Journal of the European Ceramic Society

JF - Journal of the European Ceramic Society

IS - 5

ER -

Study of the lithium insertion and de-insertion in perovskite praseodymium bismuth lithium titanate

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Keywords

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