Separation of N-C5H12-C9H20 Paraffins using boehmite by inverse Gas Chromatography

José L. Contreras-Larios; Antonia Infantes-Molina; Luís A. Negrete-Melo; Juan M. Labadie-Suárez; Hernani T. Yee-Madeira; Miguel A. Autie-Pérez; Enrique Rodríguez-Castellón

doi:10.3390/app9091810

Separation of N-C₅H₁₂-C₉H₂₀ Paraffins using boehmite by inverse Gas Chromatography

José L. Contreras-Larios, Antonia Infantes-Molina, Luís A. Negrete-Melo, Juan M. Labadie-Suárez, Hernani T. Yee-Madeira, Miguel A. Autie-Pérez, Enrique Rodríguez-Castellón

Escuela Superior de Física y Matemáticas (ESFM)

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The separation of a mixture of C5-C9 n-paraffins was achieved by Inverse Gas Chromatography (IGC) by using boehmite; AlO(OH), in a packed column with short exposure times and temperatures; from 45 °C to 52 °C. The boehmite was characterized by XRD; ATG; SEM; IR spectroscopy and N₂ adsorption. The material exhibited a low crystalline boehmite (AlOOH) structure and presented high hydration (pseudoboehmite). The reverse gas chromatography measurements showed that the elution temperatures of the C5-C9 n-paraffins were low compared with those obtained for other adsorbents. The differential heat of adsorption values ensures the satisfactory separation of the components in the C5-C9 mixture under suitable chromatographic conditions.

Translated title of the contribution	Separación de parafinas NC 5 H 12 -C 9 H 20 utilizando boehmita por cromatografía de gases inversa
Original language	English
Article number	1810
Journal	Applied Sciences (Switzerland)
Volume	9
Issue number	9
DOIs	https://doi.org/10.3390/app9091810
State	Published - 1 May 2019

Keywords

Boehmite
Differential heat of adsorption
Inverse gas chromatography
N-C5-C9 separation

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10.3390/app9091810

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title = "Separation of N-C5H12-C9H20 Paraffins using boehmite by inverse Gas Chromatography",

abstract = "The separation of a mixture of C5-C9 n-paraffins was achieved by Inverse Gas Chromatography (IGC) by using boehmite; AlO(OH), in a packed column with short exposure times and temperatures; from 45 °C to 52 °C. The boehmite was characterized by XRD; ATG; SEM; IR spectroscopy and N2 adsorption. The material exhibited a low crystalline boehmite (AlOOH) structure and presented high hydration (pseudoboehmite). The reverse gas chromatography measurements showed that the elution temperatures of the C5-C9 n-paraffins were low compared with those obtained for other adsorbents. The differential heat of adsorption values ensures the satisfactory separation of the components in the C5-C9 mixture under suitable chromatographic conditions.",

keywords = "Boehmite, Differential heat of adsorption, Inverse gas chromatography, N-C5-C9 separation",

author = "Contreras-Larios, {Jos{\'e} L.} and Antonia Infantes-Molina and Negrete-Melo, {Lu{\'i}s A.} and Labadie-Su{\'a}rez, {Juan M.} and Yee-Madeira, {Hernani T.} and Autie-P{\'e}rez, {Miguel A.} and Enrique Rodr{\'i}guez-Castell{\'o}n",

note = "Publisher Copyright: {\textcopyright} 2019 by the authors.",

year = "2019",

month = may,

day = "1",

doi = "10.3390/app9091810",

language = "Ingl{\'e}s",

volume = "9",

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T1 - Separation of N-C5H12-C9H20 Paraffins using boehmite by inverse Gas Chromatography

AU - Contreras-Larios, José L.

AU - Infantes-Molina, Antonia

AU - Negrete-Melo, Luís A.

AU - Labadie-Suárez, Juan M.

AU - Yee-Madeira, Hernani T.

AU - Autie-Pérez, Miguel A.

AU - Rodríguez-Castellón, Enrique

PY - 2019/5/1

Y1 - 2019/5/1

N2 - The separation of a mixture of C5-C9 n-paraffins was achieved by Inverse Gas Chromatography (IGC) by using boehmite; AlO(OH), in a packed column with short exposure times and temperatures; from 45 °C to 52 °C. The boehmite was characterized by XRD; ATG; SEM; IR spectroscopy and N2 adsorption. The material exhibited a low crystalline boehmite (AlOOH) structure and presented high hydration (pseudoboehmite). The reverse gas chromatography measurements showed that the elution temperatures of the C5-C9 n-paraffins were low compared with those obtained for other adsorbents. The differential heat of adsorption values ensures the satisfactory separation of the components in the C5-C9 mixture under suitable chromatographic conditions.

AB - The separation of a mixture of C5-C9 n-paraffins was achieved by Inverse Gas Chromatography (IGC) by using boehmite; AlO(OH), in a packed column with short exposure times and temperatures; from 45 °C to 52 °C. The boehmite was characterized by XRD; ATG; SEM; IR spectroscopy and N2 adsorption. The material exhibited a low crystalline boehmite (AlOOH) structure and presented high hydration (pseudoboehmite). The reverse gas chromatography measurements showed that the elution temperatures of the C5-C9 n-paraffins were low compared with those obtained for other adsorbents. The differential heat of adsorption values ensures the satisfactory separation of the components in the C5-C9 mixture under suitable chromatographic conditions.

KW - Boehmite

KW - Differential heat of adsorption

KW - Inverse gas chromatography

KW - N-C5-C9 separation

UR - http://www.scopus.com/inward/record.url?scp=85067196336&partnerID=8YFLogxK

U2 - 10.3390/app9091810

DO - 10.3390/app9091810

M3 - Artículo

AN - SCOPUS:85067196336

SN - 2076-3417

VL - 9

JO - Applied Sciences (Switzerland)

JF - Applied Sciences (Switzerland)

IS - 9

M1 - 1810

ER -

Separation of N-C₅H₁₂-C₉H₂₀ Paraffins using boehmite by inverse Gas Chromatography

Abstract

Keywords

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