Abstract
An electron paramagnetic resonance (EPR) study in the polycrystalline magnetoelectric YCrO3 is carried out at X-band (8.8-9.8 GHz) in the 300-510 K temperature range. For all the temperatures, the EPR spectra show a single broad line attributable to Cr3+ (S = 3/2) ions. The onset of the ferro-paraelectric transition has been determined from the temperature dependence of three main parameters deduced from the EPR spectra: the peak-to-peak linewidth (ΔHpp), the integrated intensity (I EPR) and the g-factor; these parameters indicate a behavior in agreement with a diffuse phase transition. Low-field microwave absorption (LFMA) is used to give a further knowledge on this material; where this technique also gives evidence of the ferro-paraelectric transition.
Original language | English |
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Pages (from-to) | L331-L335 |
Journal | Journal of Alloys and Compounds |
Volume | 509 |
Issue number | 35 |
DOIs | |
State | Published - 1 Sep 2011 |
Keywords
- Electron paramagnetic resonance
- Ferro-paraelectric transition
- Magnetoelectric
- Non-resonant microwave absorption