TY - JOUR
T1 - Relationship between global indices of reactivity, electrodonating and electroaccepting powers, and the hammet constant in isatoic anhydride derivatives
AU - Durand-Niconoff, J. S.
AU - Cruz-Kuri, L.
AU - Matus, M. H.
AU - Correa-Basurto, J.
AU - Cruz-Sánchez, J. S.
AU - Ramos-Morales, F. R.
N1 - Funding Information:
This work was supported by grants from PROMEP/ 103.5/08/1073 to FRRM, CONACYT-México 62488 to JCB and financial support through the Programa de Repatriación: MOD-ORD-70-08 PCI-1054-11-08 for MHM.
PY - 2011/9
Y1 - 2011/9
N2 - The possible correlation between Hammett's constant (σp), a characteristic parameter of functional groups with electrodonating or electroaccepting properties, and two indices of global reactivity were calculated in the gas phase. Parameters associated to a set of 22 structural variants of isatoic anhydride (2H-3, 1-benzoxazin-2,4(1H)-dione, ISA), replaced with diverse functional groups, were explored applying linear and quadratic statistical models for numerical analysis of the results.
AB - The possible correlation between Hammett's constant (σp), a characteristic parameter of functional groups with electrodonating or electroaccepting properties, and two indices of global reactivity were calculated in the gas phase. Parameters associated to a set of 22 structural variants of isatoic anhydride (2H-3, 1-benzoxazin-2,4(1H)-dione, ISA), replaced with diverse functional groups, were explored applying linear and quadratic statistical models for numerical analysis of the results.
KW - Global reactivity
KW - Hammett constant
KW - Isatoic anhydride (ISA)
UR - http://www.scopus.com/inward/record.url?scp=80053896411&partnerID=8YFLogxK
U2 - 10.1007/s12039-011-0119-y
DO - 10.1007/s12039-011-0119-y
M3 - Artículo
SN - 0974-3626
VL - 123
SP - 719
EP - 725
JO - Journal of Chemical Sciences
JF - Journal of Chemical Sciences
IS - 5
ER -