Reduction of nickel ions in mordenites with different SiO 2/Al2O3 molar ratios

V. Petranovskii, A. Pestryakov, M. A. Herandez, F. Chavez Rivas, R. Zamorano Ulloa, G. Berlier, S. Coluccia, A. Simakov

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

The aim of present work was to study the influence of SiO 2/Al2O3 molar ratio (MR) on nickel behavior in the mordenites with wide variation of MR during reduction in hydrogen flow. It was found that during reduction treatment variation of MR in mordenite from 10 to 206 influences reducibility and mobility of reduced nickel species. Stability of the reduced samples during storage in air at ambient conditions also depends on molar ratio. Variation of MR of mordenite does not change crystal structure, but results in different ionic properties. This effect is explained by variation of acidity of zeolite matrix in line with variation of chemical composition.

Translated title of the contributionReducción de iones de níquel en mordenitas con diferentes relaciones molares SiO 2 /Al 2 O 3
Original languageEnglish
Title of host publicationProceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012
DOIs
StatePublished - 2012
Event2012 7th International Forum on Strategic Technology, IFOST 2012 - Tomsk, Russian Federation
Duration: 18 Sep 201221 Sep 2012

Publication series

NameProceedings - 2012 7th International Forum on Strategic Technology, IFOST 2012

Conference

Conference2012 7th International Forum on Strategic Technology, IFOST 2012
Country/TerritoryRussian Federation
CityTomsk
Period18/09/1221/09/12

Keywords

  • SiO/AlO molar ratio
  • mordenite
  • nanoparticles
  • nickel
  • zeolites

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