Reduction of chromium oxtde from liquid slags

Research output: Contribution to conferencePaperpeer-review

Abstract

Experimental and theoretical work was performed to estimate the effect of slag basicity and amount of reducing agents on the reduction of chromium oxide from the slag which interacted with molten steel at 1600°C. The slag system contained CaO, MgO, SiO 2, CaF 2 and Cr 2O 3 together with Fe-alloys (Fe-Si and Fe-Si-Mg). The CaF 2 and MgO contents in the slags were 10 mass % each; Cr 2O 3 was 25%. The amount of the ferroalloys ranged from 12.5 to 50 g per 100 g of slag. The (CaO+MgO)/SiO 2 ratio was held at 1 and 2. The Cr yield was determined using both Fe-alloys as reducing agents. Some estimations were made to determine the theoretical effect of temperature, slag basicity, (CaO+MgO)/SiO 2, and amount of reducing agents in the slag on the chromium recovery. The FACT (Facility for the Analysis of Chemical Thermodynamics) computational package is used to determine the equilibrium between the slag and molten steel.

Original languageEnglish
Pages663-668
Number of pages6
StatePublished - 2005
Externally publishedYes
Event2005 TMS Annual Meeting - San Francisco, CA, United States
Duration: 13 Feb 200517 Feb 2005

Conference

Conference2005 TMS Annual Meeting
Country/TerritoryUnited States
CitySan Francisco, CA
Period13/02/0517/02/05

Keywords

  • Chromium oxide
  • Recovery
  • Slag
  • Stainless steel

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