Proton transfer in the solid state: Reactions of organic acids and amines

José Fernandez-Bertran; Juan C. Alvarez; Edilso Reguera

doi:10.1016/s0167-2738(97)00479-7

Proton transfer in the solid state: Reactions of organic acids and amines

José Fernandez-Bertran, Juan C. Alvarez, Edilso Reguera

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

Grinding of crystalline organic acids and amines leads to proton transfer with ammonium salt formation or to hydrogen bonded complexes. Formation of amides is not achieved with these reagents even under strong impact. The mechanochemical processes were monitored by IR spectroscopy. Thirteen acids and four amines covering a wide range of acidity, basicity and hardness were employed.

Original language	English
Pages (from-to)	129-135
Number of pages	7
Journal	Solid State Ionics
Volume	106
Issue number	1-2
DOIs	https://doi.org/10.1016/s0167-2738(97)00479-7
State	Published - 1 Feb 1998
Externally published	Yes

Keywords

Ammonium salts
Mechanochemistry

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10.1016/s0167-2738(97)00479-7

Cite this

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title = "Proton transfer in the solid state: Reactions of organic acids and amines",

abstract = "Grinding of crystalline organic acids and amines leads to proton transfer with ammonium salt formation or to hydrogen bonded complexes. Formation of amides is not achieved with these reagents even under strong impact. The mechanochemical processes were monitored by IR spectroscopy. Thirteen acids and four amines covering a wide range of acidity, basicity and hardness were employed.",

keywords = "Ammonium salts, Mechanochemistry",

author = "Jos{\'e} Fernandez-Bertran and Alvarez, {Juan C.} and Edilso Reguera",

year = "1998",

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T1 - Proton transfer in the solid state

T2 - Reactions of organic acids and amines

AU - Fernandez-Bertran, José

AU - Alvarez, Juan C.

AU - Reguera, Edilso

PY - 1998/2/1

Y1 - 1998/2/1

N2 - Grinding of crystalline organic acids and amines leads to proton transfer with ammonium salt formation or to hydrogen bonded complexes. Formation of amides is not achieved with these reagents even under strong impact. The mechanochemical processes were monitored by IR spectroscopy. Thirteen acids and four amines covering a wide range of acidity, basicity and hardness were employed.

AB - Grinding of crystalline organic acids and amines leads to proton transfer with ammonium salt formation or to hydrogen bonded complexes. Formation of amides is not achieved with these reagents even under strong impact. The mechanochemical processes were monitored by IR spectroscopy. Thirteen acids and four amines covering a wide range of acidity, basicity and hardness were employed.

KW - Ammonium salts

KW - Mechanochemistry

UR - http://www.scopus.com/inward/record.url?scp=0032003392&partnerID=8YFLogxK

U2 - 10.1016/s0167-2738(97)00479-7

DO - 10.1016/s0167-2738(97)00479-7

M3 - Artículo

SN - 0167-2738

VL - 106

SP - 129

EP - 135

JO - Solid State Ionics

JF - Solid State Ionics

IS - 1-2

ER -

Proton transfer in the solid state: Reactions of organic acids and amines

Abstract

Keywords

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