Polysllane-Metal Interactions. Photochemical Deollgomerizations and Base Treatment Migrations from Iron to Cyclopentadienyl Ligands1

Keith H. Pannell; Jorge Cervantes; Carlos Hernandez; Jeff Cassias; Steven Vincent

doi:10.1021/om00136a039

Polysllane-Metal Interactions. Photochemical Deollgomerizations and Base Treatment Migrations from Iron to Cyclopentadienyl Ligands¹

Keith H. Pannell, Jorge Cervantes, Carlos Hernandez, Jeff Cassias, Steven Vincent

Research output: Contribution to journal › Article › peer-review

159 Scopus citations

Abstract

Iron (Fp) derivatives of polysilanes have been shown to deoligomerize photochemically to yield Monosilyl iron complexes and to migrate from iron to the cyclopentadienyl ligand upon treatment with n-butyllithium. The migratory aptitude of various polysilanes has been determined. Photochemical treatment of the migrated products does not lead to deoligomerization. Infrared and ²⁹Si NMR data are reported.

Original language	English
Pages (from-to)	1056-1057
Number of pages	2
Journal	Organometallics
Volume	5
Issue number	5
DOIs	https://doi.org/10.1021/om00136a039
State	Published - 1986
Externally published	Yes

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title = "Polysllane-Metal Interactions. Photochemical Deollgomerizations and Base Treatment Migrations from Iron to Cyclopentadienyl Ligands1",

abstract = "Iron (Fp) derivatives of polysilanes have been shown to deoligomerize photochemically to yield Monosilyl iron complexes and to migrate from iron to the cyclopentadienyl ligand upon treatment with n-butyllithium. The migratory aptitude of various polysilanes has been determined. Photochemical treatment of the migrated products does not lead to deoligomerization. Infrared and 29Si NMR data are reported.",

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year = "1986",

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T1 - Polysllane-Metal Interactions. Photochemical Deollgomerizations and Base Treatment Migrations from Iron to Cyclopentadienyl Ligands1

AU - Pannell, Keith H.

AU - Cervantes, Jorge

AU - Hernandez, Carlos

AU - Cassias, Jeff

AU - Vincent, Steven

PY - 1986

Y1 - 1986

N2 - Iron (Fp) derivatives of polysilanes have been shown to deoligomerize photochemically to yield Monosilyl iron complexes and to migrate from iron to the cyclopentadienyl ligand upon treatment with n-butyllithium. The migratory aptitude of various polysilanes has been determined. Photochemical treatment of the migrated products does not lead to deoligomerization. Infrared and 29Si NMR data are reported.

AB - Iron (Fp) derivatives of polysilanes have been shown to deoligomerize photochemically to yield Monosilyl iron complexes and to migrate from iron to the cyclopentadienyl ligand upon treatment with n-butyllithium. The migratory aptitude of various polysilanes has been determined. Photochemical treatment of the migrated products does not lead to deoligomerization. Infrared and 29Si NMR data are reported.

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U2 - 10.1021/om00136a039

DO - 10.1021/om00136a039

M3 - Artículo

AN - SCOPUS:0039434389

SN - 0276-7333

VL - 5

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JO - Organometallics

JF - Organometallics

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ER -

Polysllane-Metal Interactions. Photochemical Deollgomerizations and Base Treatment Migrations from Iron to Cyclopentadienyl Ligands¹

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