Polarization reversal in BaTiO3 nanostructures synthesized by microwave-assisted hydrothermal method

Ivan Velasco-Davalos, Fabian Ambriz-Vargas, Carlos Gómez-Yáñez, Reji Thomas, Andreas Ruediger

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

Ferroelectric BaTiO3 nanostructures and thin films were deposited by a microwave assisted hydrothermal process at low temperatures (<250 °C) on metallic Pt/Al2O3/SiO2/Si and Nb:SrTiO3 (100) substrates. TiO2 nanoparticles dispersed in the Ba(OH)2 alkaline solution are used as the precursors withoutany mineralizers. The incorporation of H2O2 into precursor solution served as a strong oxidant and catalyst for the uniform nucleation of BaTiO3 on the substrate surface. The polycrystalline and epitaxial nature of the films were confirmed by atomic force microscopy and x-ray diffraction studies. We report the ferroelectric behavior of BaTiO3 films on Nb:SrTiO3 (100) substrates by piezoresponse force microscopy.

Original languageEnglish
Pages (from-to)268-274
Number of pages7
JournalJournal of Alloys and Compounds
Volume667
DOIs
StatePublished - 15 May 2016
Externally publishedYes

Keywords

  • BaTiO
  • Ferroelectric properties
  • Hydrothermal synthesis
  • Microwave-assisted hydrothermal
  • Piezo force microscopy (PFM)

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