Abstract
Very thin layers of Si were grown in between silicon nitride layers using Plasma Enhanced Chemical Vapor Deposition (PECVD) technique and SiH 2Cl 2/H 2/NH 3 mixtures. Deposition conditions were selected to favor Si cluster formation. Room Temperature Photoluminescence (RT-PL) and optical transmission in different ranges were used to evaluate the optical and structural properties of the films. Scanning Electron Microscopy (SEM) of the cross section of cleaved samples allowed to observe a clear pattern of Si clusters embedded in the SiN matrix. The UV-VIS absorption spectra present two band edges. We assume that the higher band gap is due to the amorphous Si clusters. RT-PL spectra are characterized by two broad bands: one centered at 1.5 eV and the other at 2.1 eV. The broad luminescence centered at 2.1 eV could be associated with the higher band gap observed in absorption spectrum. After vacuum annealing of the samples at 400°C, the band at 2.1 eV disappears.
Translated title of the contribution | Propiedades ópticas y morfológicas de estructuras multicapa amorfas de SiN x /Si cultivadas mediante deposición química de vapor mejorada con plasma |
---|---|
Original language | English |
Pages (from-to) | 3698-3701 |
Number of pages | 4 |
Journal | Physica Status Solidi C: Conferences |
Volume | 2 |
Issue number | 10 |
DOIs | |
State | Published - 2005 |