TY - JOUR
T1 - On the interactions of potassium bromide with alkali fluorides
AU - Valor, A.
AU - Fernández-Bertrán, J.
AU - Radilla, J.
PY - 2001
Y1 - 2001
N2 - The interactions of alkali fluorides (LiF, NaF, KF, CsF) with potassium bromide (KBr) by milling and by crystallization from water solutions have been studied by X-ray diffraction and IR techniques. KBr reacts with CsF according to CsF + KBr → KF + CsBr. With LiF and NaF, KBr does not react. With KF, KBr forms a very hygroscopic solid in which KF partially dissolves in the water of hydration and also forms the crystalline phase KF·2H2O.
AB - The interactions of alkali fluorides (LiF, NaF, KF, CsF) with potassium bromide (KBr) by milling and by crystallization from water solutions have been studied by X-ray diffraction and IR techniques. KBr reacts with CsF according to CsF + KBr → KF + CsBr. With LiF and NaF, KBr does not react. With KF, KBr forms a very hygroscopic solid in which KF partially dissolves in the water of hydration and also forms the crystalline phase KF·2H2O.
KW - Alkali fluorides
KW - KBr interactions
KW - Mechanochemistry
UR - http://www.scopus.com/inward/record.url?scp=0035182588&partnerID=8YFLogxK
U2 - 10.1016/S0022-1139(00)00387-0
DO - 10.1016/S0022-1139(00)00387-0
M3 - Artículo
SN - 0022-1139
VL - 107
SP - 137
EP - 139
JO - Journal of Fluorine Chemistry
JF - Journal of Fluorine Chemistry
IS - 1
ER -