On a CVD-formed carbon nitrogen (C3N) film doped with Cu and Zn

Roberto C. Dante; Luis Lartundo-Rojas; Pablo Martín-Ramos; Pedro Chamorro-Posada; Dario Rutto; Denisse G. Dante; José Vázquez-Cabo; Óscar Rubiños-López

doi:10.1080/1536383X.2021.1938001

On a CVD-formed carbon nitrogen (C₃N) film doped with Cu and Zn

Roberto C. Dante, Luis Lartundo-Rojas, Pablo Martín-Ramos, Pedro Chamorro-Posada, Dario Rutto, Denisse G. Dante, José Vázquez-Cabo, Óscar Rubiños-López

Centro de Nanociencias y Micro y Nanotecnologías (CNMN)

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A carbon nitrogen film was formed by chemical vapor deposition on a brass sheet starting from cyanurate of melamine as a precursor, at a temperature of 600 °C. The film was easily detached, and thoroughly characterized by means of various techniques, including X-ray photoelectron spectroscopy, X-ray diffraction, UV-Vis and infrared spectroscopies, and scanning and transmission microscopy. The material exhibited a layered structure, with many particles of zinc and copper compounds embedded on the surface. The band gap was found to be 2.06 eV, much lower than that of conventional g-C₃N₄, with values between 3.0 and 2.7 eV. The formula is close to that of C₃N, also known as bidimensional polyaniline.

Original language	English
Pages (from-to)	306-313
Number of pages	8
Journal	Fullerenes Nanotubes and Carbon Nanostructures
Volume	30
Issue number	2
DOIs	https://doi.org/10.1080/1536383X.2021.1938001
State	Published - 2022

Keywords

CN
Carbon nitride
carbon nitrogen film
doped carbon nitrogen film

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10.1080/1536383X.2021.1938001

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title = "On a CVD-formed carbon nitrogen (C3N) film doped with Cu and Zn",

abstract = "A carbon nitrogen film was formed by chemical vapor deposition on a brass sheet starting from cyanurate of melamine as a precursor, at a temperature of 600 °C. The film was easily detached, and thoroughly characterized by means of various techniques, including X-ray photoelectron spectroscopy, X-ray diffraction, UV-Vis and infrared spectroscopies, and scanning and transmission microscopy. The material exhibited a layered structure, with many particles of zinc and copper compounds embedded on the surface. The band gap was found to be 2.06 eV, much lower than that of conventional g-C3N4, with values between 3.0 and 2.7 eV. The formula is close to that of C3N, also known as bidimensional polyaniline.",

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doi = "10.1080/1536383X.2021.1938001",

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volume = "30",

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journal = "Fullerenes Nanotubes and Carbon Nanostructures",

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T1 - On a CVD-formed carbon nitrogen (C3N) film doped with Cu and Zn

AU - Dante, Roberto C.

AU - Lartundo-Rojas, Luis

AU - Martín-Ramos, Pablo

AU - Chamorro-Posada, Pedro

AU - Rutto, Dario

AU - Dante, Denisse G.

AU - Vázquez-Cabo, José

AU - Rubiños-López, Óscar

PY - 2022

Y1 - 2022

N2 - A carbon nitrogen film was formed by chemical vapor deposition on a brass sheet starting from cyanurate of melamine as a precursor, at a temperature of 600 °C. The film was easily detached, and thoroughly characterized by means of various techniques, including X-ray photoelectron spectroscopy, X-ray diffraction, UV-Vis and infrared spectroscopies, and scanning and transmission microscopy. The material exhibited a layered structure, with many particles of zinc and copper compounds embedded on the surface. The band gap was found to be 2.06 eV, much lower than that of conventional g-C3N4, with values between 3.0 and 2.7 eV. The formula is close to that of C3N, also known as bidimensional polyaniline.

AB - A carbon nitrogen film was formed by chemical vapor deposition on a brass sheet starting from cyanurate of melamine as a precursor, at a temperature of 600 °C. The film was easily detached, and thoroughly characterized by means of various techniques, including X-ray photoelectron spectroscopy, X-ray diffraction, UV-Vis and infrared spectroscopies, and scanning and transmission microscopy. The material exhibited a layered structure, with many particles of zinc and copper compounds embedded on the surface. The band gap was found to be 2.06 eV, much lower than that of conventional g-C3N4, with values between 3.0 and 2.7 eV. The formula is close to that of C3N, also known as bidimensional polyaniline.

KW - CN

KW - Carbon nitride

KW - carbon nitrogen film

KW - doped carbon nitrogen film

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U2 - 10.1080/1536383X.2021.1938001

DO - 10.1080/1536383X.2021.1938001

M3 - Artículo

AN - SCOPUS:85107793417

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JO - Fullerenes Nanotubes and Carbon Nanostructures

JF - Fullerenes Nanotubes and Carbon Nanostructures

IS - 2

ER -

On a CVD-formed carbon nitrogen (C₃N) film doped with Cu and Zn

Abstract

Keywords

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