TY - JOUR
T1 - Modeling the dynamic viscosity of associating and polar fluids via the use of density scaling
AU - Macías-Salinas, Ricardo
AU - Flores-Granados, Miguel Angel
AU - Díaz-Cruz, Manuela
AU - García-Sánchez, Fernando
N1 - Publisher Copyright:
© 2017 Elsevier B.V.
PY - 2018/2/25
Y1 - 2018/2/25
N2 - It is well-known that certain dynamical properties such as the dielectric relaxation times and the viscosity of liquids can be graphically superpositioned onto a single master curve as a function of the thermodynamic potential (ργ/T), where T is the temperature, ρ is the density, and γ is a state-independent scaling exponent. We presently applied the aforementioned thermodynamic scaling to the viscosity of typical hydrogen-bonding formers and polar fluids such as water, hydrogen sulfide, ammonia, methanol and an ionic liquid: [bmim][PF6]. Unlike previous studies on density scaling of transport properties, a more suitable reduction and normalization of the viscosity was introduced here in order to obtain improved correlations of viscosity over much wider temperature and pressure ranges encompassing the zero-density limit, the high-density region, the gas-liquid saturation line and the vicinity of the critical point. A calculation procedure is also described here to optimize the value of the scaling exponent γ that ensures the best super-positioning of all experimental isotherms considered for each substance.
AB - It is well-known that certain dynamical properties such as the dielectric relaxation times and the viscosity of liquids can be graphically superpositioned onto a single master curve as a function of the thermodynamic potential (ργ/T), where T is the temperature, ρ is the density, and γ is a state-independent scaling exponent. We presently applied the aforementioned thermodynamic scaling to the viscosity of typical hydrogen-bonding formers and polar fluids such as water, hydrogen sulfide, ammonia, methanol and an ionic liquid: [bmim][PF6]. Unlike previous studies on density scaling of transport properties, a more suitable reduction and normalization of the viscosity was introduced here in order to obtain improved correlations of viscosity over much wider temperature and pressure ranges encompassing the zero-density limit, the high-density region, the gas-liquid saturation line and the vicinity of the critical point. A calculation procedure is also described here to optimize the value of the scaling exponent γ that ensures the best super-positioning of all experimental isotherms considered for each substance.
KW - Density scaling
KW - Dynamic viscosity
KW - Modeling
KW - Polar fluids
UR - http://www.scopus.com/inward/record.url?scp=85034093983&partnerID=8YFLogxK
U2 - 10.1016/j.fluid.2017.10.032
DO - 10.1016/j.fluid.2017.10.032
M3 - Artículo
SN - 0378-3812
VL - 458
SP - 16
EP - 29
JO - Fluid Phase Equilibria
JF - Fluid Phase Equilibria
ER -