Abstract
The mechanochemical transformations of Ag, Hg and Pb cyano complexes (ferro- and ferricyanides, cobalticyanides, nitroprussides, hexacyanoplatinates and tetracyanonickellates) during milling and pressing with KBr have been studied using IR, XRD and Mossbauer techniques as sensors. Exchange of K+ and the heavy metal cations is observed in all cases.
Original language | English |
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Pages (from-to) | 89-98 |
Number of pages | 10 |
Journal | Spectroscopy Letters |
Volume | 30 |
Issue number | 1 |
DOIs | |
State | Published - 1997 |
Externally published | Yes |
Keywords
- Cyano complexes
- IR spectra
- Ion exchange reactions
- Mechanochemistry