Mechanochemical transformations of Ag, Hg and Pb cyanometallates in KBr pressed disks

E. Reguera, J. Fernández-Bertrán

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

The mechanochemical transformations of Ag, Hg and Pb cyano complexes (ferro- and ferricyanides, cobalticyanides, nitroprussides, hexacyanoplatinates and tetracyanonickellates) during milling and pressing with KBr have been studied using IR, XRD and Mossbauer techniques as sensors. Exchange of K+ and the heavy metal cations is observed in all cases.

Original languageEnglish
Pages (from-to)89-98
Number of pages10
JournalSpectroscopy Letters
Volume30
Issue number1
DOIs
StatePublished - 1997
Externally publishedYes

Keywords

  • Cyano complexes
  • IR spectra
  • Ion exchange reactions
  • Mechanochemistry

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