Mechanochemical reactions in alkali halide pressed disks

J. Fernández-Bertrán; E. Reguera

doi:10.1016/s0167-2738(96)00443-2

Mechanochemical reactions in alkali halide pressed disks

J. Fernández-Bertrán, E. Reguera

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

Mechanochemical reactions that take place when milling and pressing analytes with KBr to form a disk suitable for IR spectral work are reviewed. The topic is extended to other alkali halides matrices. The literature from 1952 is surveyed from an analytical point of view. Several reactions are discussed at length with emphasis on the nature of the products. The mechanism and the factors affecting the mechanochemical changes are discussed in detail for copper sulphate, alkaline and transition metal ferricyanides, and Ag, Hg and Pb salts.

Original language	English
Pages (from-to)	139-146
Number of pages	8
Journal	Solid State Ionics
Volume	93
Issue number	1-2
DOIs	https://doi.org/10.1016/s0167-2738(96)00443-2
State	Published - Dec 1996
Externally published	Yes

Keywords

Exchange reactions
Infrared spectra
Mechanochemistry
Oxidation-reduction reactions
Solid solutions

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10.1016/s0167-2738(96)00443-2

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abstract = "Mechanochemical reactions that take place when milling and pressing analytes with KBr to form a disk suitable for IR spectral work are reviewed. The topic is extended to other alkali halides matrices. The literature from 1952 is surveyed from an analytical point of view. Several reactions are discussed at length with emphasis on the nature of the products. The mechanism and the factors affecting the mechanochemical changes are discussed in detail for copper sulphate, alkaline and transition metal ferricyanides, and Ag, Hg and Pb salts.",

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author = "J. Fern{\'a}ndez-Bertr{\'a}n and E. Reguera",

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AU - Reguera, E.

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AB - Mechanochemical reactions that take place when milling and pressing analytes with KBr to form a disk suitable for IR spectral work are reviewed. The topic is extended to other alkali halides matrices. The literature from 1952 is surveyed from an analytical point of view. Several reactions are discussed at length with emphasis on the nature of the products. The mechanism and the factors affecting the mechanochemical changes are discussed in detail for copper sulphate, alkaline and transition metal ferricyanides, and Ag, Hg and Pb salts.

KW - Exchange reactions

KW - Infrared spectra

KW - Mechanochemistry

KW - Oxidation-reduction reactions

KW - Solid solutions

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U2 - 10.1016/s0167-2738(96)00443-2

DO - 10.1016/s0167-2738(96)00443-2

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ER -

Mechanochemical reactions in alkali halide pressed disks

Abstract

Keywords

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