TY - JOUR
T1 - Materials for Hydrogen Storage in Nanocavities
T2 - Design criteria
AU - Reguera, E.
N1 - Funding Information:
This study was partially supported by the projects ICyTDF PIFUTP08-158 and SEP-CONACyT 61541.
PY - 2009/11
Y1 - 2009/11
N2 - The adsorption potential for a given adsorbate depends of both, material surface and adsorbate properties. In this contribution the possible guest-host interactions for H2 within a cavity or on a surface are discussed considering the molecule physical properties. Five different interactions contribute to the adsorption forces for this molecule: 1) quadrupole moment interaction with the local electric field gradient; 1) electron cloud polarization by a charge center; 3) dispersive forces (van der Waals); 4) quadrupole moment versus quadrupole moment between neighboring H2 molecules, and, 5) H2 coordination to a metal center. The relative importance of these five interactions for the hydrogen storage in nanocavities is discussed from experimental evidences in order to extract materials design criteria for molecular hydrogen storage.
AB - The adsorption potential for a given adsorbate depends of both, material surface and adsorbate properties. In this contribution the possible guest-host interactions for H2 within a cavity or on a surface are discussed considering the molecule physical properties. Five different interactions contribute to the adsorption forces for this molecule: 1) quadrupole moment interaction with the local electric field gradient; 1) electron cloud polarization by a charge center; 3) dispersive forces (van der Waals); 4) quadrupole moment versus quadrupole moment between neighboring H2 molecules, and, 5) H2 coordination to a metal center. The relative importance of these five interactions for the hydrogen storage in nanocavities is discussed from experimental evidences in order to extract materials design criteria for molecular hydrogen storage.
UR - http://www.scopus.com/inward/record.url?scp=71849120167&partnerID=8YFLogxK
U2 - 10.1016/j.ijhydene.2009.09.037
DO - 10.1016/j.ijhydene.2009.09.037
M3 - Artículo
SN - 0360-3199
VL - 34
SP - 9163
EP - 9167
JO - International Journal of Hydrogen Energy
JF - International Journal of Hydrogen Energy
IS - 22
ER -