Mössbauer spectroscopic study of Prussian Blue from different provenances

E. Reguera; J. Fernández-Bertrán; A. Dago; C. Díaz

doi:10.1007/BF02418604

Mössbauer spectroscopic study of Prussian Blue from different provenances

E. Reguera, J. Fernández-Bertrán, A. Dago, C. Díaz

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39 Scopus citations

Abstract

Ferric ferrocyanides synthesized from different sources of ferric cations and ferrocyanide anions and those derived from ferrous ferricyanide, ferrous ferrocyanide and ferric ferricyanide have been studied using Mössbauer and XRD techniques. Structural information of the effect of the provenance on the properties of the final compound is obtained. Significant correlations between isomer shift and quadrupole splitting of inner and outer iron cations have been observed.

Original language	English
Pages (from-to)	295-308
Number of pages	14
Journal	Hyperfine Interactions
Volume	73
Issue number	3-4
DOIs	https://doi.org/10.1007/BF02418604
State	Published - Oct 1992
Externally published	Yes

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abstract = "Ferric ferrocyanides synthesized from different sources of ferric cations and ferrocyanide anions and those derived from ferrous ferricyanide, ferrous ferrocyanide and ferric ferricyanide have been studied using M{\"o}ssbauer and XRD techniques. Structural information of the effect of the provenance on the properties of the final compound is obtained. Significant correlations between isomer shift and quadrupole splitting of inner and outer iron cations have been observed.",

author = "E. Reguera and J. Fern{\'a}ndez-Bertr{\'a}n and A. Dago and C. D{\'i}az",

year = "1992",

month = oct,

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AU - Reguera, E.

AU - Fernández-Bertrán, J.

AU - Dago, A.

AU - Díaz, C.

PY - 1992/10

Y1 - 1992/10

N2 - Ferric ferrocyanides synthesized from different sources of ferric cations and ferrocyanide anions and those derived from ferrous ferricyanide, ferrous ferrocyanide and ferric ferricyanide have been studied using Mössbauer and XRD techniques. Structural information of the effect of the provenance on the properties of the final compound is obtained. Significant correlations between isomer shift and quadrupole splitting of inner and outer iron cations have been observed.

AB - Ferric ferrocyanides synthesized from different sources of ferric cations and ferrocyanide anions and those derived from ferrous ferricyanide, ferrous ferrocyanide and ferric ferricyanide have been studied using Mössbauer and XRD techniques. Structural information of the effect of the provenance on the properties of the final compound is obtained. Significant correlations between isomer shift and quadrupole splitting of inner and outer iron cations have been observed.

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U2 - 10.1007/BF02418604

DO - 10.1007/BF02418604

M3 - Artículo

SN - 0304-3834

VL - 73

SP - 295

EP - 308

JO - Hyperfine Interactions

JF - Hyperfine Interactions

IS - 3-4

ER -

Mössbauer spectroscopic study of Prussian Blue from different provenances

Abstract

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