Lewis Acid-Catalyzed Ring-Opening Alcoholysis of Cyclohexene Oxide: The Role of Open Metal Sites in the Bi(III)-based Metal-Organic Framework SU-101

Juan L. Obeso; J. Gabriel Flores; Catalina V. Flores; Reyna Rios-Escobedo; Julia Aguilar-Pliego; A. Ken Inge; José Antonio de los Reyes; Ricardo A. Peralta; Ilich A. Ibarra; Carolina Leyva

doi:10.1002/cctc.202300471

Lewis Acid-Catalyzed Ring-Opening Alcoholysis of Cyclohexene Oxide: The Role of Open Metal Sites in the Bi(III)-based Metal-Organic Framework SU-101

Juan L. Obeso, J. Gabriel Flores, Catalina V. Flores, Reyna Rios-Escobedo, Julia Aguilar-Pliego, A. Ken Inge, José Antonio de los Reyes, Ricardo A. Peralta, Ilich A. Ibarra, Carolina Leyva

Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada (CICATA), Unidad Legaria

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

SU-101 was screened for the acid-catalyzed ring-opening alcoholysis of cyclohexene oxide. Results indicated access to open metal sites within SU-101, a fundamental requirement (Lewis acid Bi⁺³ sites) for this reaction. In addition, SU-101 exhibited high chemical stability, demonstrated by retaining its crystalline structure after the reaction. The cyclohexene conversion was estimated to be 99.8, 96.8, and 14.3 % at 40 °C for methanol, ethanol, and propanol, respectively. Also, SU-101 demonstrated an outstanding catalytic cyclability performance for five cycles without losing catalytic activity.

Original language	English
Article number	e202300471
Journal	ChemCatChem
Volume	15
Issue number	13
DOIs	https://doi.org/10.1002/cctc.202300471
State	Published - 7 Jul 2023

Keywords

Lewis acids
alcoholysis
heterogeneous catalysis
metal-organic frameworks
open-metal sites

Access to Document

10.1002/cctc.202300471

Cite this

Obeso, J. L., Gabriel Flores, J., Flores, C. V., Rios-Escobedo, R., Aguilar-Pliego, J., Ken Inge, A., Antonio de los Reyes, J., Peralta, R. A., Ibarra, I. A., & Leyva, C. (2023). Lewis Acid-Catalyzed Ring-Opening Alcoholysis of Cyclohexene Oxide: The Role of Open Metal Sites in the Bi(III)-based Metal-Organic Framework SU-101. ChemCatChem, 15(13), Article e202300471. https://doi.org/10.1002/cctc.202300471

@article{d2f7d7b6b36640f19edc422279b86dbf,

title = "Lewis Acid-Catalyzed Ring-Opening Alcoholysis of Cyclohexene Oxide: The Role of Open Metal Sites in the Bi(III)-based Metal-Organic Framework SU-101",

abstract = "SU-101 was screened for the acid-catalyzed ring-opening alcoholysis of cyclohexene oxide. Results indicated access to open metal sites within SU-101, a fundamental requirement (Lewis acid Bi+3 sites) for this reaction. In addition, SU-101 exhibited high chemical stability, demonstrated by retaining its crystalline structure after the reaction. The cyclohexene conversion was estimated to be 99.8, 96.8, and 14.3 % at 40 °C for methanol, ethanol, and propanol, respectively. Also, SU-101 demonstrated an outstanding catalytic cyclability performance for five cycles without losing catalytic activity.",

keywords = "Lewis acids, alcoholysis, heterogeneous catalysis, metal-organic frameworks, open-metal sites",

author = "Obeso, {Juan L.} and {Gabriel Flores}, J. and Flores, {Catalina V.} and Reyna Rios-Escobedo and Julia Aguilar-Pliego and {Ken Inge}, A. and {Antonio de los Reyes}, Jos{\'e} and Peralta, {Ricardo A.} and Ibarra, {Ilich A.} and Carolina Leyva",

note = "Publisher Copyright: {\textcopyright} 2023 The Authors. ChemCatChem published by Wiley-VCH GmbH.",

year = "2023",

month = jul,

day = "7",

doi = "10.1002/cctc.202300471",

language = "Ingl{\'e}s",

volume = "15",

journal = "ChemCatChem",

issn = "1867-3880",

publisher = "Wiley - VCH Verlag GmbH & CO. KGaA",

number = "13",

}

Obeso, JL, Gabriel Flores, J, Flores, CV, Rios-Escobedo, R, Aguilar-Pliego, J, Ken Inge, A, Antonio de los Reyes, J, Peralta, RA, Ibarra, IA & Leyva, C 2023, 'Lewis Acid-Catalyzed Ring-Opening Alcoholysis of Cyclohexene Oxide: The Role of Open Metal Sites in the Bi(III)-based Metal-Organic Framework SU-101', ChemCatChem, vol. 15, no. 13, e202300471. https://doi.org/10.1002/cctc.202300471

TY - JOUR

T1 - Lewis Acid-Catalyzed Ring-Opening Alcoholysis of Cyclohexene Oxide

T2 - The Role of Open Metal Sites in the Bi(III)-based Metal-Organic Framework SU-101

AU - Obeso, Juan L.

AU - Gabriel Flores, J.

AU - Flores, Catalina V.

AU - Rios-Escobedo, Reyna

AU - Aguilar-Pliego, Julia

AU - Ken Inge, A.

AU - Antonio de los Reyes, José

AU - Peralta, Ricardo A.

AU - Ibarra, Ilich A.

AU - Leyva, Carolina

PY - 2023/7/7

Y1 - 2023/7/7

N2 - SU-101 was screened for the acid-catalyzed ring-opening alcoholysis of cyclohexene oxide. Results indicated access to open metal sites within SU-101, a fundamental requirement (Lewis acid Bi+3 sites) for this reaction. In addition, SU-101 exhibited high chemical stability, demonstrated by retaining its crystalline structure after the reaction. The cyclohexene conversion was estimated to be 99.8, 96.8, and 14.3 % at 40 °C for methanol, ethanol, and propanol, respectively. Also, SU-101 demonstrated an outstanding catalytic cyclability performance for five cycles without losing catalytic activity.

AB - SU-101 was screened for the acid-catalyzed ring-opening alcoholysis of cyclohexene oxide. Results indicated access to open metal sites within SU-101, a fundamental requirement (Lewis acid Bi+3 sites) for this reaction. In addition, SU-101 exhibited high chemical stability, demonstrated by retaining its crystalline structure after the reaction. The cyclohexene conversion was estimated to be 99.8, 96.8, and 14.3 % at 40 °C for methanol, ethanol, and propanol, respectively. Also, SU-101 demonstrated an outstanding catalytic cyclability performance for five cycles without losing catalytic activity.

KW - Lewis acids

KW - alcoholysis

KW - heterogeneous catalysis

KW - metal-organic frameworks

KW - open-metal sites

UR - http://www.scopus.com/inward/record.url?scp=85160681987&partnerID=8YFLogxK

U2 - 10.1002/cctc.202300471

DO - 10.1002/cctc.202300471

M3 - Artículo

AN - SCOPUS:85160681987

SN - 1867-3880

VL - 15

JO - ChemCatChem

JF - ChemCatChem

IS - 13

M1 - e202300471

ER -

Lewis Acid-Catalyzed Ring-Opening Alcoholysis of Cyclohexene Oxide: The Role of Open Metal Sites in the Bi(III)-based Metal-Organic Framework SU-101

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this