TY - JOUR
T1 - Ionic liquids with carboxylic-acid-derived anions evaluated as corrosion inhibitors under dynamic conditions
AU - Likhanova, Natalya V.
AU - Arellanes-Lozada, Paulina
AU - Olivares-Xometl, Octavio
AU - Lijanova, Irina V.
AU - Arriola-Morales, Janette
AU - Mendoza-Hérnandez, José Carlos
AU - Corro, Grisel
N1 - Publisher Copyright:
© 2019 The Authors.
PY - 2019
Y1 - 2019
N2 - The present work deals with the evaluation of three novel ionic liquids (ILs): triethylmethyl ammonium laurate (TAL), triethylmethyl ammonium anthranilate (TAA) and triethylmethyl ammonium oleate (TAO). These compounds were evaluated as corrosion inhibitors (CIs) of API 5L X52 steel in 0.5 M H 2 SO 4 by means of electrochemical techniques such as polarization resistance (Rp) and Tafel polarization curves. The electrochemical studies were performed at stationary state (N Re = 0) and transitory regime (N Re = 3375 and 4500) with concentrations ranging from 10 to 100 ppm. The maximal inhibition efficiencies (IEs) for TAL (78 %) and TAA (73 %) were obtained at 100 ppm and NRe = 4500 whereas for TAO (63 %) the IE was reached at NRe =3375. These results confirmed that the IE is also a function of N Re . Furthermore, the Langmuir adsorption isotherm indicated that the IL molecules were adsorbed on the metal surface through a physical phenomenon. From the analysis of the results, a mechanism through which the ILs inhibit the corrosion of API 5L X52 steel in 0.5 M H 2 SO 4 was proposed.
AB - The present work deals with the evaluation of three novel ionic liquids (ILs): triethylmethyl ammonium laurate (TAL), triethylmethyl ammonium anthranilate (TAA) and triethylmethyl ammonium oleate (TAO). These compounds were evaluated as corrosion inhibitors (CIs) of API 5L X52 steel in 0.5 M H 2 SO 4 by means of electrochemical techniques such as polarization resistance (Rp) and Tafel polarization curves. The electrochemical studies were performed at stationary state (N Re = 0) and transitory regime (N Re = 3375 and 4500) with concentrations ranging from 10 to 100 ppm. The maximal inhibition efficiencies (IEs) for TAL (78 %) and TAA (73 %) were obtained at 100 ppm and NRe = 4500 whereas for TAO (63 %) the IE was reached at NRe =3375. These results confirmed that the IE is also a function of N Re . Furthermore, the Langmuir adsorption isotherm indicated that the IL molecules were adsorbed on the metal surface through a physical phenomenon. From the analysis of the results, a mechanism through which the ILs inhibit the corrosion of API 5L X52 steel in 0.5 M H 2 SO 4 was proposed.
KW - Corrosion behaviour
KW - Electrochemical techniques
KW - Ionic liquid
KW - Surface analysis
UR - http://www.scopus.com/inward/record.url?scp=85064009221&partnerID=8YFLogxK
U2 - 10.20964/2019.03.71
DO - 10.20964/2019.03.71
M3 - Artículo
SN - 1452-3981
VL - 14
SP - 2655
EP - 2671
JO - International Journal of Electrochemical Science
JF - International Journal of Electrochemical Science
IS - 3
ER -