TY - JOUR
T1 - Ga and Al containing MCM-41 mesoporous molecular sieves
T2 - Structure and catalytic performance for the 4,6 dimethyldibenzothiophene hydrodesulfurization
AU - Martínez-Belmonte, E.
AU - Aguilar, J.
AU - Gutierrez, M.
AU - Montoya, J. A.
AU - De Los Reyes, J. A.
AU - Torres, M.
AU - Chen, L. F.
N1 - Funding Information:
We are grateful to the SEP-CONACyT Program (Mexico) for the financial aid through grant 42204-Y and for a postgraduate scholarship (E. Martinez-Belmonte). Partial funding by IMP is also acknowledged. And thanks Dr. J. Arenas by TEM analysis of the samples in this work.
PY - 2013/9/1
Y1 - 2013/9/1
N2 - MCM-41 type materials containing Al and Ga (Al-Ga-MCM-41) were prepared by a synthesis gel using cethyltrimethylammonium chloride as surfactant. In the preparation, Si/(Al + Ga) ratios were 21, 27 and 32 in the gel, maintaining the concentration of Al constant. The structures of the materials were characterized by X-ray diffraction (XRD), nitrogen physisorption, Fourier transform infrared spectroscopy (FTIR) of adsorbed pyridine, 27Al MAS NMR, 29Si MAS NMR and energy dispersive analysis of X-ray (EDX). Al-Ga-MCM-41 exhibited prominent characteristics as supports for the Ni-Mo-S type catalysts used in the hydrodesulfurization of 4,6-dimethyldibenzothiphene (4,6 DMDBT). The presence of Ga was detected by TEM with a resolution of 1.9 Å point to point; therefore the Ga is in the lattice. The amount of Ga in the support enhanced the activity of the catalysts and modified the products distribution. The maximum catalytic activity and direct desulfurization capability was achieved on the catalyst NiMo/Al-Ga-MCM-41 with Si/(Al + Ga) = 32 molar ratio.
AB - MCM-41 type materials containing Al and Ga (Al-Ga-MCM-41) were prepared by a synthesis gel using cethyltrimethylammonium chloride as surfactant. In the preparation, Si/(Al + Ga) ratios were 21, 27 and 32 in the gel, maintaining the concentration of Al constant. The structures of the materials were characterized by X-ray diffraction (XRD), nitrogen physisorption, Fourier transform infrared spectroscopy (FTIR) of adsorbed pyridine, 27Al MAS NMR, 29Si MAS NMR and energy dispersive analysis of X-ray (EDX). Al-Ga-MCM-41 exhibited prominent characteristics as supports for the Ni-Mo-S type catalysts used in the hydrodesulfurization of 4,6-dimethyldibenzothiphene (4,6 DMDBT). The presence of Ga was detected by TEM with a resolution of 1.9 Å point to point; therefore the Ga is in the lattice. The amount of Ga in the support enhanced the activity of the catalysts and modified the products distribution. The maximum catalytic activity and direct desulfurization capability was achieved on the catalyst NiMo/Al-Ga-MCM-41 with Si/(Al + Ga) = 32 molar ratio.
KW - 4,6-Dimethyldibenzothiophene
KW - Gallium
KW - Hydrodesulfurization
KW - Isomerization
KW - MCM-41
KW - Nickel-molybdenum sulfides
UR - http://www.scopus.com/inward/record.url?scp=84879989331&partnerID=8YFLogxK
U2 - 10.1016/j.cattod.2012.08.028
DO - 10.1016/j.cattod.2012.08.028
M3 - Artículo
AN - SCOPUS:84879989331
SN - 0920-5861
VL - 212
SP - 45
EP - 51
JO - Catalysis Today
JF - Catalysis Today
ER -