Formation of carbonylrhenium cryptates with alkali metal cations: Coordination chemistry studies of [Ph2P(E)NP(E)Ph2] -, e = O, S, Se towards ReBr(CO)5

Ricardo Rodríguez-Palacios; Marisol Reyes-Lezama; Lucila Márquez-Pallares; Ana Adela Lemus-Santana; Obdulia Sánchez-Guadarrama; Herbert Höpfl; Noé Zúñiga-Villarreal

doi:10.1016/j.poly.2010.08.011

Formation of carbonylrhenium cryptates with alkali metal cations: Coordination chemistry studies of [Ph₂P(E)NP(E)Ph₂] ^-, e = O, S, Se towards ReBr(CO)₅

Ricardo Rodríguez-Palacios, Marisol Reyes-Lezama, Lucila Márquez-Pallares, Ana Adela Lemus-Santana, Obdulia Sánchez-Guadarrama, Herbert Höpfl, Noé Zúñiga-Villarreal

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15 Scopus citations

Abstract

Reaction of ReBr(CO)₅ with Li[Ph₂P(O)NP(O)Ph ₂] afforded the cryptate Li[Re₂(CO)₆{μ- Ph₂P(O)NP(O)Ph₂-κ²O,O'}₃]; whereas K[Ph₂P(O)NP(O)Ph₂] reacted with ReBr(CO) ₅ to give K[Re₂(CO)₆{μ-Ph ₂P(O)NP(O)Ph₂-κ²O,O′}{Ph ₂P(O)NP(O)Ph₂-κ²O,O′}₂]. Other chalcogen ligands' salts M[Ph₂P(E)NP(E)Ph₂], E = Se and S, M = K and Li gave dirhenium carbonyls with bromido and Ph ₂P(E)NP(E)Ph₂, E = Se or S bridges upon reaction with ReBr(CO)₅.

Original language	English
Pages (from-to)	3103-3110
Number of pages	8
Journal	Polyhedron
Volume	29
Issue number	16
DOIs	https://doi.org/10.1016/j.poly.2010.08.011
State	Published - 29 Oct 2010
Externally published	Yes

Keywords

Alkali metal cations
Carbonyl rhenates
Imidodichalcogenophosphinates
Inorganic ligands

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10.1016/j.poly.2010.08.011

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Rodríguez-Palacios, R., Reyes-Lezama, M., Márquez-Pallares, L., Lemus-Santana, A. A., Sánchez-Guadarrama, O., Höpfl, H., & Zúñiga-Villarreal, N. (2010). Formation of carbonylrhenium cryptates with alkali metal cations: Coordination chemistry studies of [Ph₂P(E)NP(E)Ph₂] ^-, e = O, S, Se towards ReBr(CO)₅. Polyhedron, 29(16), 3103-3110. https://doi.org/10.1016/j.poly.2010.08.011

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title = "Formation of carbonylrhenium cryptates with alkali metal cations: Coordination chemistry studies of [Ph2P(E)NP(E)Ph2] -, e = O, S, Se towards ReBr(CO)5",

abstract = "Reaction of ReBr(CO)5 with Li[Ph2P(O)NP(O)Ph 2] afforded the cryptate Li[Re2(CO)6{μ- Ph2P(O)NP(O)Ph2-κ2O,O'}3]; whereas K[Ph2P(O)NP(O)Ph2] reacted with ReBr(CO) 5 to give K[Re2(CO)6{μ-Ph 2P(O)NP(O)Ph2-κ2O,O′}{Ph 2P(O)NP(O)Ph2-κ2O,O′}2]. Other chalcogen ligands' salts M[Ph2P(E)NP(E)Ph2], E = Se and S, M = K and Li gave dirhenium carbonyls with bromido and Ph 2P(E)NP(E)Ph2, E = Se or S bridges upon reaction with ReBr(CO)5.",

keywords = "Alkali metal cations, Carbonyl rhenates, Imidodichalcogenophosphinates, Inorganic ligands",

author = "Ricardo Rodr{\'i}guez-Palacios and Marisol Reyes-Lezama and Lucila M{\'a}rquez-Pallares and Lemus-Santana, {Ana Adela} and Obdulia S{\'a}nchez-Guadarrama and Herbert H{\"o}pfl and No{\'e} Z{\'u}{\~n}iga-Villarreal",

year = "2010",

month = oct,

day = "29",

doi = "10.1016/j.poly.2010.08.011",

language = "Ingl{\'e}s",

volume = "29",

pages = "3103--3110",

journal = "Polyhedron",

issn = "0277-5387",

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Rodríguez-Palacios, R, Reyes-Lezama, M, Márquez-Pallares, L, Lemus-Santana, AA, Sánchez-Guadarrama, O, Höpfl, H & Zúñiga-Villarreal, N 2010, 'Formation of carbonylrhenium cryptates with alkali metal cations: Coordination chemistry studies of [Ph₂P(E)NP(E)Ph₂] ^-, e = O, S, Se towards ReBr(CO)₅', Polyhedron, vol. 29, no. 16, pp. 3103-3110. https://doi.org/10.1016/j.poly.2010.08.011

TY - JOUR

T1 - Formation of carbonylrhenium cryptates with alkali metal cations

T2 - Coordination chemistry studies of [Ph2P(E)NP(E)Ph2] -, e = O, S, Se towards ReBr(CO)5

AU - Rodríguez-Palacios, Ricardo

AU - Reyes-Lezama, Marisol

AU - Márquez-Pallares, Lucila

AU - Lemus-Santana, Ana Adela

AU - Sánchez-Guadarrama, Obdulia

AU - Höpfl, Herbert

AU - Zúñiga-Villarreal, Noé

PY - 2010/10/29

Y1 - 2010/10/29

N2 - Reaction of ReBr(CO)5 with Li[Ph2P(O)NP(O)Ph 2] afforded the cryptate Li[Re2(CO)6{μ- Ph2P(O)NP(O)Ph2-κ2O,O'}3]; whereas K[Ph2P(O)NP(O)Ph2] reacted with ReBr(CO) 5 to give K[Re2(CO)6{μ-Ph 2P(O)NP(O)Ph2-κ2O,O′}{Ph 2P(O)NP(O)Ph2-κ2O,O′}2]. Other chalcogen ligands' salts M[Ph2P(E)NP(E)Ph2], E = Se and S, M = K and Li gave dirhenium carbonyls with bromido and Ph 2P(E)NP(E)Ph2, E = Se or S bridges upon reaction with ReBr(CO)5.

AB - Reaction of ReBr(CO)5 with Li[Ph2P(O)NP(O)Ph 2] afforded the cryptate Li[Re2(CO)6{μ- Ph2P(O)NP(O)Ph2-κ2O,O'}3]; whereas K[Ph2P(O)NP(O)Ph2] reacted with ReBr(CO) 5 to give K[Re2(CO)6{μ-Ph 2P(O)NP(O)Ph2-κ2O,O′}{Ph 2P(O)NP(O)Ph2-κ2O,O′}2]. Other chalcogen ligands' salts M[Ph2P(E)NP(E)Ph2], E = Se and S, M = K and Li gave dirhenium carbonyls with bromido and Ph 2P(E)NP(E)Ph2, E = Se or S bridges upon reaction with ReBr(CO)5.

KW - Alkali metal cations

KW - Carbonyl rhenates

KW - Imidodichalcogenophosphinates

KW - Inorganic ligands

UR - http://www.scopus.com/inward/record.url?scp=77957981792&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2010.08.011

DO - 10.1016/j.poly.2010.08.011

M3 - Artículo

SN - 0277-5387

VL - 29

SP - 3103

EP - 3110

JO - Polyhedron

JF - Polyhedron

IS - 16

ER -

Formation of carbonylrhenium cryptates with alkali metal cations: Coordination chemistry studies of [Ph₂P(E)NP(E)Ph₂] ^-, e = O, S, Se towards ReBr(CO)₅

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Keywords

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