TY - JOUR
T1 - Experimental Determination of Gas Hydrates Dissociation Conditions in CO 2 /N 2 + Ethanol/1-Propanol/TBAB/TBAF + Water Systems
AU - Sánchez-Mora, María F.
AU - Galicia-Luna, Luis A.
AU - Pimentel-Rodas, Alfredo
AU - Mohammadi, Amir H.
N1 - Publisher Copyright:
© 2019 American Chemical Society.
PY - 2019/2/14
Y1 - 2019/2/14
N2 - The formation of gas hydrates is considered as a potential for oil and natural gas pipelines blockage and operational problems. It is also argued that gas hydrates can be considered as an alternative method to separate gases and many positive applications. The presence of additives in an aqueous solution can play an important role in determining gas hydrate formation conditions. In this work, hydrate dissociation conditions for the N 2 + ethanol + water system, the N 2 + 1-propanol + water system, and the CO 2 + tetra-butyl-ammonium fluoride (TBAF) + water system have been measured and are reported. The mass fractions of alcohols were 0.05, 0.10, 0.20, and 0.30. The mass fractions of TBAF were 0.05 and 0.10. The experimental measurements were performed using an isochoric pressure search method (synthetic nonvisual method) in the 262.87-294.52 K temperature range and 0.79-33.06 MPa pressure range. The viability of the method used was verified by the experimental determination and comparison with previously published data in the literature of hydrate dissociation conditions for the N 2 + H 2 O system, the CO 2 + C 2 H 6 O + H 2 O system, and the CO 2 + N 2 + TBAB + H 2 O system.
AB - The formation of gas hydrates is considered as a potential for oil and natural gas pipelines blockage and operational problems. It is also argued that gas hydrates can be considered as an alternative method to separate gases and many positive applications. The presence of additives in an aqueous solution can play an important role in determining gas hydrate formation conditions. In this work, hydrate dissociation conditions for the N 2 + ethanol + water system, the N 2 + 1-propanol + water system, and the CO 2 + tetra-butyl-ammonium fluoride (TBAF) + water system have been measured and are reported. The mass fractions of alcohols were 0.05, 0.10, 0.20, and 0.30. The mass fractions of TBAF were 0.05 and 0.10. The experimental measurements were performed using an isochoric pressure search method (synthetic nonvisual method) in the 262.87-294.52 K temperature range and 0.79-33.06 MPa pressure range. The viability of the method used was verified by the experimental determination and comparison with previously published data in the literature of hydrate dissociation conditions for the N 2 + H 2 O system, the CO 2 + C 2 H 6 O + H 2 O system, and the CO 2 + N 2 + TBAB + H 2 O system.
UR - http://www.scopus.com/inward/record.url?scp=85060313275&partnerID=8YFLogxK
U2 - 10.1021/acs.jced.8b00998
DO - 10.1021/acs.jced.8b00998
M3 - Artículo
SN - 0021-9568
VL - 64
SP - 763
EP - 770
JO - Journal of Chemical and Engineering Data
JF - Journal of Chemical and Engineering Data
IS - 2
ER -