Evaluation of the sulphide capacity of Na2O-containing silicate slags using a structural model

Antonio Romero-Serrano; Josué López-Rodríguez; Aurelio Hernández-Ramírez; Alejandro Cruz-Ramírez; Cancio Jiménez-Lugos; Miguel Pérez-Labra

doi:10.1080/03019233.2023.2212931

Evaluation of the sulphide capacity of Na₂O-containing silicate slags using a structural model

Antonio Romero-Serrano, Josué López-Rodríguez, Aurelio Hernández-Ramírez, Alejandro Cruz-Ramírez, Cancio Jiménez-Lugos, Miguel Pérez-Labra

Research output: Contribution to journal › Article › peer-review

Abstract

This article suggests that the sulphide capacity may be a unique property of slag that can be calculated at a given temperature and composition, even for CaO- or Na₂O-containing slags where the amount of dissolved sulphides is significant. A structural model that incorporates sulphide ions (S²⁻) in the silicate network is used to calculate the sulphide capacity of SiO₂-Na₂O binary and SiO₂-Na₂O-MO (M = Ca, Mg, Mn, Fe) ternary systems. This structural model considers the effect of substituting one metal oxide for another in ternary systems and uses only the data for the binary subsystems without any ternary adjustable parameter.

Original language	English
Pages (from-to)	1707-1716
Number of pages	10
Journal	Ironmaking and Steelmaking
Volume	50
Issue number	11
DOIs	https://doi.org/10.1080/03019233.2023.2212931
State	Published - 2023

Keywords

Sodium oxide-containing slags
sulphide capacity
thermodynamic model

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10.1080/03019233.2023.2212931

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abstract = "This article suggests that the sulphide capacity may be a unique property of slag that can be calculated at a given temperature and composition, even for CaO- or Na2O-containing slags where the amount of dissolved sulphides is significant. A structural model that incorporates sulphide ions (S2−) in the silicate network is used to calculate the sulphide capacity of SiO2-Na2O binary and SiO2-Na2O-MO (M = Ca, Mg, Mn, Fe) ternary systems. This structural model considers the effect of substituting one metal oxide for another in ternary systems and uses only the data for the binary subsystems without any ternary adjustable parameter.",

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T1 - Evaluation of the sulphide capacity of Na2O-containing silicate slags using a structural model

AU - Romero-Serrano, Antonio

AU - López-Rodríguez, Josué

AU - Hernández-Ramírez, Aurelio

AU - Cruz-Ramírez, Alejandro

AU - Jiménez-Lugos, Cancio

AU - Pérez-Labra, Miguel

PY - 2023

Y1 - 2023

N2 - This article suggests that the sulphide capacity may be a unique property of slag that can be calculated at a given temperature and composition, even for CaO- or Na2O-containing slags where the amount of dissolved sulphides is significant. A structural model that incorporates sulphide ions (S2−) in the silicate network is used to calculate the sulphide capacity of SiO2-Na2O binary and SiO2-Na2O-MO (M = Ca, Mg, Mn, Fe) ternary systems. This structural model considers the effect of substituting one metal oxide for another in ternary systems and uses only the data for the binary subsystems without any ternary adjustable parameter.

AB - This article suggests that the sulphide capacity may be a unique property of slag that can be calculated at a given temperature and composition, even for CaO- or Na2O-containing slags where the amount of dissolved sulphides is significant. A structural model that incorporates sulphide ions (S2−) in the silicate network is used to calculate the sulphide capacity of SiO2-Na2O binary and SiO2-Na2O-MO (M = Ca, Mg, Mn, Fe) ternary systems. This structural model considers the effect of substituting one metal oxide for another in ternary systems and uses only the data for the binary subsystems without any ternary adjustable parameter.

KW - Sodium oxide-containing slags

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KW - thermodynamic model

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DO - 10.1080/03019233.2023.2212931

M3 - Artículo

AN - SCOPUS:85160032438

SN - 0301-9233

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SP - 1707

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ER -

Evaluation of the sulphide capacity of Na₂O-containing silicate slags using a structural model

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Keywords

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