TY - JOUR
T1 - Enhanced photoactivity for the phenol mineralization on ZnAlLa mixed oxides prepared from calcined LDHs
AU - Tzompantzi, F.
AU - Mendoza-Damián, G.
AU - Rico, J. L.
AU - Mantilla, A.
N1 - Funding Information:
The authors are grateful to CONACyT for the financial support (Projects 154994 and 169157). Angeles Mantilla acknowledges IPN for the financial support (Project SIP 20131470). Guadalupe Mendoza Damián thanks CONACyT for the scholarship granted (Scholarship number: 252081).
PY - 2014/3
Y1 - 2014/3
N2 - ZnAlLa layered double hydroxides (La/Zn molar ratio of 0.005, 0.01 and 0.03) were synthesized by the co-precipitation method and calcined at 500 C. XRD patterns showed lamellar type materials in fresh solids (dried) and a diminishing basal parameter denoting the incorporation of La in the ZnAl LDH structure. At low content of La, XRD does not show the formation of La 2O3, which become detectable only in the sample with high La content. After calcination, the formation of zincite was detected in the LDH, indicating the destruction of the lamellar structure. The Eg band of the sample with low content of La, calculated from the UV-Vis spectra, showed a shift to low energy, while for the samples with high content of La the Eg shift is displaced to high absorption energy. Evaluation of the photoactivity in the degradation of phenol using a low intensity UV-Vis lamp (254 nm and 4400 μW/cm2), showed the maximum values in phenol mineralization 88-66% with the ZnAlLa samples, in comparison to that obtained with the ZnAl oxide (48%). These results show that ZnAlLa mixed oxides prepared from the thermal treatment of ZnAlLa LDH are promising materials for an effective phenol mineralization.
AB - ZnAlLa layered double hydroxides (La/Zn molar ratio of 0.005, 0.01 and 0.03) were synthesized by the co-precipitation method and calcined at 500 C. XRD patterns showed lamellar type materials in fresh solids (dried) and a diminishing basal parameter denoting the incorporation of La in the ZnAl LDH structure. At low content of La, XRD does not show the formation of La 2O3, which become detectable only in the sample with high La content. After calcination, the formation of zincite was detected in the LDH, indicating the destruction of the lamellar structure. The Eg band of the sample with low content of La, calculated from the UV-Vis spectra, showed a shift to low energy, while for the samples with high content of La the Eg shift is displaced to high absorption energy. Evaluation of the photoactivity in the degradation of phenol using a low intensity UV-Vis lamp (254 nm and 4400 μW/cm2), showed the maximum values in phenol mineralization 88-66% with the ZnAlLa samples, in comparison to that obtained with the ZnAl oxide (48%). These results show that ZnAlLa mixed oxides prepared from the thermal treatment of ZnAlLa LDH are promising materials for an effective phenol mineralization.
KW - Phenol mineralization
KW - Photodegradation of phenol
KW - ZnAlLa LDH
KW - ZnAlLa mixed oxides
UR - http://www.scopus.com/inward/record.url?scp=84889662892&partnerID=8YFLogxK
U2 - 10.1016/j.cattod.2013.07.014
DO - 10.1016/j.cattod.2013.07.014
M3 - Artículo
AN - SCOPUS:84889662892
SN - 0920-5861
VL - 220-222
SP - 56
EP - 60
JO - Catalysis Today
JF - Catalysis Today
ER -