TY - JOUR
T1 - Electrochemical behavior of Ni xW 1-x materials as catalyst for hydrogen evolution reaction in alkaline media
AU - Oliver-Tolentino, Miguel A.
AU - Arce-Estrada, Elsa M.
AU - Cortés-Escobedo, Claudia A.
AU - Bolarín-Miro, Ana M.
AU - Sánchez-De Jesús, Félix
AU - González-Huerta, Rosa De G.
AU - Manzo-Robledo, Arturo
PY - 2012/9/25
Y1 - 2012/9/25
N2 - In the present work, results of electrochemical evaluation, as well as morphological and structural characterization of Ni xW 1-x materials with x = 0.77, 0.64, 0.4, 0.19 and 0.07 processed by means of high energy ball milling from high purity powders are presented. Also, the electrocatalytic performance on the hydrogen evolution reaction (HER) of the Ni xW 1-x materials evaluated by linear polarization and cyclic voltammetry techniques in alkaline media at room temperature is discussed. The structural and morphological characterization of the as-prepared materials was carried out using X-ray diffraction (XRD) and scanning electron microscopy (SEM). Results indicated a small-particle clusters and solid solution formation. According to the kinetics parameters the best electrocatalytic activity was observed at Ni 64W 36.
AB - In the present work, results of electrochemical evaluation, as well as morphological and structural characterization of Ni xW 1-x materials with x = 0.77, 0.64, 0.4, 0.19 and 0.07 processed by means of high energy ball milling from high purity powders are presented. Also, the electrocatalytic performance on the hydrogen evolution reaction (HER) of the Ni xW 1-x materials evaluated by linear polarization and cyclic voltammetry techniques in alkaline media at room temperature is discussed. The structural and morphological characterization of the as-prepared materials was carried out using X-ray diffraction (XRD) and scanning electron microscopy (SEM). Results indicated a small-particle clusters and solid solution formation. According to the kinetics parameters the best electrocatalytic activity was observed at Ni 64W 36.
KW - Electrocatalysis
KW - HER
KW - Mechanical alloying
KW - NiW
UR - http://www.scopus.com/inward/record.url?scp=84865689181&partnerID=8YFLogxK
U2 - 10.1016/j.jallcom.2011.12.086
DO - 10.1016/j.jallcom.2011.12.086
M3 - Artículo
AN - SCOPUS:84865689181
SN - 0925-8388
VL - 536
SP - S245-S249
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
IS - SUPPL.1
ER -