Electrocatalysis of the oxygen reduction reaction on Pd0.5M 0.4Pt0.1 (M=Cu,Ni,Fe,Co) nanoparticles

F. Godínez-Salomón; J. M. Hallen López; O. Solorza-Feria

doi:10.1149/1.3660649

Electrocatalysis of the oxygen reduction reaction on Pd_0.5M _0.4Pt_0.1 (M=Cu,Ni,Fe,Co) nanoparticles

F. Godínez-Salomón, J. M. Hallen López, O. Solorza-Feria

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

1 Scopus citations

Abstract

This work presents the study of the electrocatalytic activity of the oxygen reduction reaction (ORR) in 0.5M H₂SO₄ on dispersed nanoparticles of different ternary Pd_0.5M_0.4Pt _0.1 (M = Cu, Ni, Fe and Co) alloys, through thin-film rotating disk electrode (TF-RDE). Transmission electron microscopy (TEM) showed homogeneous distribution of nanoparticles between 17-45 nm in sizes. The catalysts containing Co, Ni or Fe, show equivalent behavior to Pd alone, however, the Pd_0.5Cu_0.4Pt_0.1 catalyst showed similar specific activity (μA cm² real) but twice specific mass activity (mA mg^-1) compared to Pt synthesized under the same experimental condition.

Original language	English
Title of host publication	MES 2011
Subtitle of host publication	Electrochemistry as a Tool for Sustainable Development
Publisher	Electrochemical Society Inc.
Pages	541-548
Number of pages	8
Edition	1
ISBN (Electronic)	9781566779401
ISBN (Print)	9781607682981
DOIs	https://doi.org/10.1149/1.3660649
State	Published - 2011
Externally published	Yes
Event	26th National Meeting of the Mexican Electrochemical Society, MES 2011 and the 4th Meeting of the ECS Mexican Section - 220th ECS Meeting - Mexico City, Mexico Duration: 29 May 2011 → 3 Jun 2011

Publication series

Name	ECS Transactions
Number	1
Volume	36
ISSN (Print)	1938-5862
ISSN (Electronic)	1938-6737

Conference

Conference	26th National Meeting of the Mexican Electrochemical Society, MES 2011 and the 4th Meeting of the ECS Mexican Section - 220th ECS Meeting
Country/Territory	Mexico
City	Mexico City
Period	29/05/11 → 3/06/11

Access to Document

10.1149/1.3660649

Cite this

@inproceedings{dba769977a424a1cb370d3ec57da814f,

title = "Electrocatalysis of the oxygen reduction reaction on Pd0.5M 0.4Pt0.1 (M=Cu,Ni,Fe,Co) nanoparticles",

abstract = "This work presents the study of the electrocatalytic activity of the oxygen reduction reaction (ORR) in 0.5M H2SO4 on dispersed nanoparticles of different ternary Pd0.5M0.4Pt 0.1 (M = Cu, Ni, Fe and Co) alloys, through thin-film rotating disk electrode (TF-RDE). Transmission electron microscopy (TEM) showed homogeneous distribution of nanoparticles between 17-45 nm in sizes. The catalysts containing Co, Ni or Fe, show equivalent behavior to Pd alone, however, the Pd0.5Cu0.4Pt0.1 catalyst showed similar specific activity (μA cm2 real) but twice specific mass activity (mA mg-1) compared to Pt synthesized under the same experimental condition.",

author = "F. God{\'i}nez-Salom{\'o}n and {Hallen L{\'o}pez}, {J. M.} and O. Solorza-Feria",

year = "2011",

doi = "10.1149/1.3660649",

language = "Ingl{\'e}s",

isbn = "9781607682981",

series = "ECS Transactions",

publisher = "Electrochemical Society Inc.",

number = "1",

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booktitle = "MES 2011",

edition = "1",

note = "26th National Meeting of the Mexican Electrochemical Society, MES 2011 and the 4th Meeting of the ECS Mexican Section - 220th ECS Meeting ; Conference date: 29-05-2011 Through 03-06-2011",

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Godínez-Salomón, F, Hallen López, JM & Solorza-Feria, O 2011, Electrocatalysis of the oxygen reduction reaction on Pd_0.5M _0.4Pt_0.1 (M=Cu,Ni,Fe,Co) nanoparticles. in MES 2011: Electrochemistry as a Tool for Sustainable Development. 1 edn, ECS Transactions, no. 1, vol. 36, Electrochemical Society Inc., pp. 541-548, 26th National Meeting of the Mexican Electrochemical Society, MES 2011 and the 4th Meeting of the ECS Mexican Section - 220th ECS Meeting, Mexico City, Mexico, 29/05/11. https://doi.org/10.1149/1.3660649

Electrocatalysis of the oxygen reduction reaction on Pd_0.5M _0.4Pt_0.1 (M=Cu,Ni,Fe,Co) nanoparticles. / Godínez-Salomón, F.; Hallen López, J. M.; Solorza-Feria, O.
MES 2011: Electrochemistry as a Tool for Sustainable Development. 1. ed. Electrochemical Society Inc., 2011. p. 541-548 (ECS Transactions; Vol. 36, No. 1).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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AB - This work presents the study of the electrocatalytic activity of the oxygen reduction reaction (ORR) in 0.5M H2SO4 on dispersed nanoparticles of different ternary Pd0.5M0.4Pt 0.1 (M = Cu, Ni, Fe and Co) alloys, through thin-film rotating disk electrode (TF-RDE). Transmission electron microscopy (TEM) showed homogeneous distribution of nanoparticles between 17-45 nm in sizes. The catalysts containing Co, Ni or Fe, show equivalent behavior to Pd alone, however, the Pd0.5Cu0.4Pt0.1 catalyst showed similar specific activity (μA cm2 real) but twice specific mass activity (mA mg-1) compared to Pt synthesized under the same experimental condition.

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