Electro-reduction of nitrate and nitrite ions on carbon-supported Pt nanoparticles

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8 Scopus citations

Abstract

Synthesized carbon-supported Pt nanoparticles (10 wt% Pt/C) and their commercial counterpart (40 wt% Pt-Etek/C) have been used to study the electrochemical reduction of NOx- ions at different concentrations in alkaline and acid pH. A comparative study between nanostructured and massif platinum was evaluated. Cycling Voltammetry (CV), Rotating Disc Electrode (RDE) and Differential Mass Spectrometry (DEMS) were used for this purpose. Stationary current-potential curves indicate that the adsorption-desorption phenomena take place in two different regions of potential: the electrochemical reduction of NOx- ions for potentials ranging from -0.60 to -0.95 V/SCE, and the hydrogen evolution reaction (HER) at potential lower than -0.95 V/SCE. These results confirmed that the reduction of NOx- ions follows the order Pt/C > Pt-Etek/C > Pt-massif. DEMS demonstrated the formation of nitrogen species such as N2, NO, N2O and NO2.

Original languageEnglish
Title of host publicationECS Transactions - MES 23
Subtitle of host publicationElectrochemistry, Nanotechnology, and Biomaterials - 23rd MES Meeting
PublisherElectrochemical Society Inc.
Pages385-393
Number of pages9
Edition1
ISBN (Electronic)9781566776851
ISBN (Print)9781615672882
DOIs
StatePublished - 2008
Externally publishedYes
EventMES 23: Electrochemistry, Nanotechnology, and Biomaterials - 23rd MES Meeting - Ensenada, Baja California, Mexico
Duration: 1 Jun 20086 Jun 2008

Publication series

NameECS Transactions
Number1
Volume15
ISSN (Print)1938-5862
ISSN (Electronic)1938-6737

Conference

ConferenceMES 23: Electrochemistry, Nanotechnology, and Biomaterials - 23rd MES Meeting
Country/TerritoryMexico
CityEnsenada, Baja California
Period1/06/086/06/08

Keywords

  • Cyclic voltammetry
  • DEMS
  • Hydrogen evolution reaction
  • Nanoparticles
  • Nitrate reduction

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