Elect roca tal) tic Performance of Palladium-Based Elect rocatalysts Supported on Carbon Nanotubes for Formic Acid Oxidation.

L. Juárez-Marmolejo; M. G.Montes De Oca-Yemha; M. Palomar-Pardavé; M. Romero-Romo; A. Ezeta-Mejía; E. M. Arce-Estrada; S. Pérez-Rodríguez; M. J. Lázaro

doi:10.1149/09208.0317ecst

Elect roca tal) tic Performance of Palladium-Based Elect rocatalysts Supported on Carbon Nanotubes for Formic Acid Oxidation.

L. Juárez-Marmolejo, M. G.Montes De Oca-Yemha, M. Palomar-Pardavé, M. Romero-Romo, A. Ezeta-Mejía, E. M. Arce-Estrada, S. Pérez-Rodríguez, M. J. Lázaro

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

1 Scopus citations

Abstract

In the present work, Pd and PdFe nanoparticies supported on CNT with and without functionalization (CNT and CNTox) were used for Formic Acid Oxidation Reaction (FAOR) in acid media. Electrocatalysts were synthesized by the borohydride reduction method with 20 wt.% metal loading. The CNTs were synthesized by the methane catalytic decomposition, and subjected to an oxidation treatment with nitric acid, named as CNTox. The morphology, composition and structural properties were studied by Transmission Electron Microscopy (TEM), Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDX) and X-Ray Diffraction (XRD). The FAOR was evaluated in acid media in a conventional three-electrode cell by means of cyclic voltammetry and chronoamperometry. From the steady state current density, it was found that Pd and PdFe supported at CNTox allowed improving the catalytic activity in comparison with the non-oxidized support.

Original language	English
Title of host publication	Polymer Electrolyte Fuel Cells and Electrolyzers 19, PEFC and E 19
Editors	K. Swider-Lyons, H. Uchida, F. Buechi, W. E. Mustain, B. S. Pivovar, P. N. Pintauro, A. Z. Weber, D. Jones, H. Gasteiger, C. A. Rice, P. Strasser, E. Kjeang, K. Shinohara, S. Mitsushima, Y.-T. Kim, T. J. Schmidt, J. M. Fenton, R. A. Mantz, B. Lakshmanan, H. Xu
Publisher	Electrochemical Society Inc.
Pages	317-324
Number of pages	8
Edition	8
ISBN (Electronic)	9781607688822
ISBN (Print)	9781607688822
DOIs	https://doi.org/10.1149/09208.0317ecst
State	Published - 2019
Externally published	Yes
Event	Symposium on Polymer Electrolyte Fuel Cells and Electrolyzers 19, PEFC and E 2019 - 236th ECS Meeting - Atlanta, United States Duration: 13 Oct 2019 → 17 Oct 2019

Publication series

Name	ECS Transactions
Number	8
Volume	92
ISSN (Print)	1938-6737
ISSN (Electronic)	1938-5862

Conference

Conference	Symposium on Polymer Electrolyte Fuel Cells and Electrolyzers 19, PEFC and E 2019 - 236th ECS Meeting
Country/Territory	United States
City	Atlanta
Period	13/10/19 → 17/10/19

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10.1149/09208.0317ecst

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Juárez-Marmolejo, L., De Oca-Yemha, M. G. M., Palomar-Pardavé, M., Romero-Romo, M., Ezeta-Mejía, A., Arce-Estrada, E. M., Pérez-Rodríguez, S., & Lázaro, M. J. (2019). Elect roca tal) tic Performance of Palladium-Based Elect rocatalysts Supported on Carbon Nanotubes for Formic Acid Oxidation. In K. Swider-Lyons, H. Uchida, F. Buechi, W. E. Mustain, B. S. Pivovar, P. N. Pintauro, A. Z. Weber, D. Jones, H. Gasteiger, C. A. Rice, P. Strasser, E. Kjeang, K. Shinohara, S. Mitsushima, Y.-T. Kim, T. J. Schmidt, J. M. Fenton, R. A. Mantz, B. Lakshmanan, & H. Xu (Eds.), Polymer Electrolyte Fuel Cells and Electrolyzers 19, PEFC and E 19 (8 ed., pp. 317-324). (ECS Transactions; Vol. 92, No. 8). Electrochemical Society Inc.. https://doi.org/10.1149/09208.0317ecst

Juárez-Marmolejo, L. ; De Oca-Yemha, M. G.Montes ; Palomar-Pardavé, M. et al. / Elect roca tal) tic Performance of Palladium-Based Elect rocatalysts Supported on Carbon Nanotubes for Formic Acid Oxidation. Polymer Electrolyte Fuel Cells and Electrolyzers 19, PEFC and E 19. editor / K. Swider-Lyons ; H. Uchida ; F. Buechi ; W. E. Mustain ; B. S. Pivovar ; P. N. Pintauro ; A. Z. Weber ; D. Jones ; H. Gasteiger ; C. A. Rice ; P. Strasser ; E. Kjeang ; K. Shinohara ; S. Mitsushima ; Y.-T. Kim ; T. J. Schmidt ; J. M. Fenton ; R. A. Mantz ; B. Lakshmanan ; H. Xu. 8. ed. Electrochemical Society Inc., 2019. pp. 317-324 (ECS Transactions; 8).

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title = "Elect roca tal) tic Performance of Palladium-Based Elect rocatalysts Supported on Carbon Nanotubes for Formic Acid Oxidation.",

abstract = "In the present work, Pd and PdFe nanoparticies supported on CNT with and without functionalization (CNT and CNTox) were used for Formic Acid Oxidation Reaction (FAOR) in acid media. Electrocatalysts were synthesized by the borohydride reduction method with 20 wt.% metal loading. The CNTs were synthesized by the methane catalytic decomposition, and subjected to an oxidation treatment with nitric acid, named as CNTox. The morphology, composition and structural properties were studied by Transmission Electron Microscopy (TEM), Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDX) and X-Ray Diffraction (XRD). The FAOR was evaluated in acid media in a conventional three-electrode cell by means of cyclic voltammetry and chronoamperometry. From the steady state current density, it was found that Pd and PdFe supported at CNTox allowed improving the catalytic activity in comparison with the non-oxidized support.",

author = "L. Ju{\'a}rez-Marmolejo and {De Oca-Yemha}, {M. G.Montes} and M. Palomar-Pardav{\'e} and M. Romero-Romo and A. Ezeta-Mej{\'i}a and Arce-Estrada, {E. M.} and S. P{\'e}rez-Rodr{\'i}guez and L{\'a}zaro, {M. J.}",

note = "Publisher Copyright: {\textcopyright} The Electrochemical Society.; Symposium on Polymer Electrolyte Fuel Cells and Electrolyzers 19, PEFC and E 2019 - 236th ECS Meeting ; Conference date: 13-10-2019 Through 17-10-2019",

year = "2019",

doi = "10.1149/09208.0317ecst",

language = "Ingl{\'e}s",

isbn = "9781607688822",

series = "ECS Transactions",

publisher = "Electrochemical Society Inc.",

number = "8",

pages = "317--324",

editor = "K. Swider-Lyons and H. Uchida and F. Buechi and Mustain, {W. E.} and Pivovar, {B. S.} and Pintauro, {P. N.} and Weber, {A. Z.} and D. Jones and H. Gasteiger and Rice, {C. A.} and P. Strasser and E. Kjeang and K. Shinohara and S. Mitsushima and Y.-T. Kim and Schmidt, {T. J.} and Fenton, {J. M.} and Mantz, {R. A.} and B. Lakshmanan and H. Xu",

booktitle = "Polymer Electrolyte Fuel Cells and Electrolyzers 19, PEFC and E 19",

edition = "8",

}

Juárez-Marmolejo, L, De Oca-Yemha, MGM, Palomar-Pardavé, M, Romero-Romo, M, Ezeta-Mejía, A , Arce-Estrada, EM, Pérez-Rodríguez, S & Lázaro, MJ 2019, Elect roca tal) tic Performance of Palladium-Based Elect rocatalysts Supported on Carbon Nanotubes for Formic Acid Oxidation. in K Swider-Lyons, H Uchida, F Buechi, WE Mustain, BS Pivovar, PN Pintauro, AZ Weber, D Jones, H Gasteiger, CA Rice, P Strasser, E Kjeang, K Shinohara, S Mitsushima, Y-T Kim, TJ Schmidt, JM Fenton, RA Mantz, B Lakshmanan & H Xu (eds), Polymer Electrolyte Fuel Cells and Electrolyzers 19, PEFC and E 19. 8 edn, ECS Transactions, no. 8, vol. 92, Electrochemical Society Inc., pp. 317-324, Symposium on Polymer Electrolyte Fuel Cells and Electrolyzers 19, PEFC and E 2019 - 236th ECS Meeting, Atlanta, United States, 13/10/19. https://doi.org/10.1149/09208.0317ecst

Elect roca tal) tic Performance of Palladium-Based Elect rocatalysts Supported on Carbon Nanotubes for Formic Acid Oxidation. / Juárez-Marmolejo, L.; De Oca-Yemha, M. G.Montes; Palomar-Pardavé, M. et al.
Polymer Electrolyte Fuel Cells and Electrolyzers 19, PEFC and E 19. ed. / K. Swider-Lyons; H. Uchida; F. Buechi; W. E. Mustain; B. S. Pivovar; P. N. Pintauro; A. Z. Weber; D. Jones; H. Gasteiger; C. A. Rice; P. Strasser; E. Kjeang; K. Shinohara; S. Mitsushima; Y.-T. Kim; T. J. Schmidt; J. M. Fenton; R. A. Mantz; B. Lakshmanan; H. Xu. 8. ed. Electrochemical Society Inc., 2019. p. 317-324 (ECS Transactions; Vol. 92, No. 8).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Elect roca tal) tic Performance of Palladium-Based Elect rocatalysts Supported on Carbon Nanotubes for Formic Acid Oxidation.

AU - Juárez-Marmolejo, L.

AU - De Oca-Yemha, M. G.Montes

AU - Palomar-Pardavé, M.

AU - Romero-Romo, M.

AU - Ezeta-Mejía, A.

AU - Arce-Estrada, E. M.

AU - Pérez-Rodríguez, S.

AU - Lázaro, M. J.

N1 - Publisher Copyright: © The Electrochemical Society.

PY - 2019

Y1 - 2019

N2 - In the present work, Pd and PdFe nanoparticies supported on CNT with and without functionalization (CNT and CNTox) were used for Formic Acid Oxidation Reaction (FAOR) in acid media. Electrocatalysts were synthesized by the borohydride reduction method with 20 wt.% metal loading. The CNTs were synthesized by the methane catalytic decomposition, and subjected to an oxidation treatment with nitric acid, named as CNTox. The morphology, composition and structural properties were studied by Transmission Electron Microscopy (TEM), Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDX) and X-Ray Diffraction (XRD). The FAOR was evaluated in acid media in a conventional three-electrode cell by means of cyclic voltammetry and chronoamperometry. From the steady state current density, it was found that Pd and PdFe supported at CNTox allowed improving the catalytic activity in comparison with the non-oxidized support.

AB - In the present work, Pd and PdFe nanoparticies supported on CNT with and without functionalization (CNT and CNTox) were used for Formic Acid Oxidation Reaction (FAOR) in acid media. Electrocatalysts were synthesized by the borohydride reduction method with 20 wt.% metal loading. The CNTs were synthesized by the methane catalytic decomposition, and subjected to an oxidation treatment with nitric acid, named as CNTox. The morphology, composition and structural properties were studied by Transmission Electron Microscopy (TEM), Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDX) and X-Ray Diffraction (XRD). The FAOR was evaluated in acid media in a conventional three-electrode cell by means of cyclic voltammetry and chronoamperometry. From the steady state current density, it was found that Pd and PdFe supported at CNTox allowed improving the catalytic activity in comparison with the non-oxidized support.

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U2 - 10.1149/09208.0317ecst

DO - 10.1149/09208.0317ecst

M3 - Contribución a la conferencia

AN - SCOPUS:85077496204

SN - 9781607688822

T3 - ECS Transactions

SP - 317

EP - 324

BT - Polymer Electrolyte Fuel Cells and Electrolyzers 19, PEFC and E 19

A2 - Swider-Lyons, K.

A2 - Uchida, H.

A2 - Buechi, F.

A2 - Mustain, W. E.

A2 - Pivovar, B. S.

A2 - Pintauro, P. N.

A2 - Weber, A. Z.

A2 - Jones, D.

A2 - Gasteiger, H.

A2 - Rice, C. A.

A2 - Strasser, P.

A2 - Kjeang, E.

A2 - Shinohara, K.

A2 - Mitsushima, S.

A2 - Kim, Y.-T.

A2 - Schmidt, T. J.

A2 - Fenton, J. M.

A2 - Mantz, R. A.

A2 - Lakshmanan, B.

A2 - Xu, H.

PB - Electrochemical Society Inc.

T2 - Symposium on Polymer Electrolyte Fuel Cells and Electrolyzers 19, PEFC and E 2019 - 236th ECS Meeting

Y2 - 13 October 2019 through 17 October 2019

ER -

Juárez-Marmolejo L, De Oca-Yemha MGM, Palomar-Pardavé M, Romero-Romo M, Ezeta-Mejía A , Arce-Estrada EM et al. Elect roca tal) tic Performance of Palladium-Based Elect rocatalysts Supported on Carbon Nanotubes for Formic Acid Oxidation. In Swider-Lyons K, Uchida H, Buechi F, Mustain WE, Pivovar BS, Pintauro PN, Weber AZ, Jones D, Gasteiger H, Rice CA, Strasser P, Kjeang E, Shinohara K, Mitsushima S, Kim YT, Schmidt TJ, Fenton JM, Mantz RA, Lakshmanan B, Xu H, editors, Polymer Electrolyte Fuel Cells and Electrolyzers 19, PEFC and E 19. 8 ed. Electrochemical Society Inc. 2019. p. 317-324. (ECS Transactions; 8). doi: 10.1149/09208.0317ecst

Elect roca tal) tic Performance of Palladium-Based Elect rocatalysts Supported on Carbon Nanotubes for Formic Acid Oxidation.

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