TY - JOUR
T1 - Efficient electrocatalytic reduction of nitrite species on zeolite modified electrode with Cu-ZSM-5
AU - Guzmán-Vargas, Ariel
AU - Oliver-Tolentino, Miguel A.
AU - Lima, Enrique
AU - Flores-Morenod, Jorge
N1 - Funding Information:
ICYTDF PICS09-321, CONACYT 101319 and SIP-IPN 20131229 projects for financial support.
PY - 2013
Y1 - 2013
N2 - The electrocatalytic reduction of nitrite has been studied on the surface of zeolite modified electrodeusing exchanged ZSM-5 with copper (ME/Cu-ZSM-5). The process of reduction and kinetics studies were investigated through cyclic voltammetry and chronoamperometry techniques. The i-E characteristics of ME/Cu-ZSM-5 presented the faradic process associated to redox couple Cu 2+/Cu+with a ΔE = 0.064 V/SCE. On the other hand, voltammetric studies showed that in presence of nitrite, the cathodic peak current of ME/Cu-ZSM-5 increases followed by a decrease in the corresponding anodic current. This indicated thatnitrite species were reduced by a cooperative effect of the acidic properties of zeolite and copper that acts as a redox mediator being immobilized on the electrode surface via an electrocatalytic mechanism. Further experiments showed that electrocatalytic activity increases as Si/Al ratio decreases, the electro-catalytic activity was improved when the material Cu-ZSM-5 was calcined prior to electrode preparation. The values of the rate constant of the catalytic reduction of nitrite and the detection limit obtained were 5.9 × 102 cm3 mol-1s -1 and 1.4 × 10-5mol L-1, respectively.
AB - The electrocatalytic reduction of nitrite has been studied on the surface of zeolite modified electrodeusing exchanged ZSM-5 with copper (ME/Cu-ZSM-5). The process of reduction and kinetics studies were investigated through cyclic voltammetry and chronoamperometry techniques. The i-E characteristics of ME/Cu-ZSM-5 presented the faradic process associated to redox couple Cu 2+/Cu+with a ΔE = 0.064 V/SCE. On the other hand, voltammetric studies showed that in presence of nitrite, the cathodic peak current of ME/Cu-ZSM-5 increases followed by a decrease in the corresponding anodic current. This indicated thatnitrite species were reduced by a cooperative effect of the acidic properties of zeolite and copper that acts as a redox mediator being immobilized on the electrode surface via an electrocatalytic mechanism. Further experiments showed that electrocatalytic activity increases as Si/Al ratio decreases, the electro-catalytic activity was improved when the material Cu-ZSM-5 was calcined prior to electrode preparation. The values of the rate constant of the catalytic reduction of nitrite and the detection limit obtained were 5.9 × 102 cm3 mol-1s -1 and 1.4 × 10-5mol L-1, respectively.
KW - Cu-ZSM-5a
KW - Electrocatalytic
KW - Nitrite
KW - Reduction
KW - Zeolite modified electrode
UR - http://www.scopus.com/inward/record.url?scp=84884234534&partnerID=8YFLogxK
U2 - 10.1016/j.electacta.2013.07.030
DO - 10.1016/j.electacta.2013.07.030
M3 - Artículo
SN - 0013-4686
VL - 108
SP - 583
EP - 590
JO - Electrochimica Acta
JF - Electrochimica Acta
ER -