TY - JOUR
T1 - Effect of Mo and Co loading in HDS catalysts supported on solvo-thermally treated ZrO2-TiO2 mixed oxides
AU - Escobar, José
AU - Barrera, María C.
AU - Reyes, José A.De Los
AU - Cortés, María A.
AU - Santes, Víctor
AU - Gómez, Elizabeth
AU - Pacheco, José G.
N1 - Funding Information:
The authors recognize financial support from Instituto Mexicano del Petróleo and UAM-Iztapalapa. They also appreciate the comments from Dr. M. Vrinat (CNRS) to improve this work.
PY - 2008/4
Y1 - 2008/4
N2 - Molybdenum (at 2.8, 3.3, 4.0 and 4.7 atoms nm-2) and cobalt (Co/(Co + Mo) ratios of 0.3, 0.4 and 0.5) were impregnated on wide-pore ZrO2-TiO2 mixed oxides (30-70) prepared with solvo-thermal treatment (80 °C, 1 day). Materials characterization comprised N2 physisorption, XRD, thermal analyses, and UV-vis DRS, Raman, and IR spectroscopies. For impregnated dried materials (non-calcined) at concentrations beyond 3.3 atom nm-2 and activated by sulfiding (H2S/H2, 400 °C) no further improvement in activity in dibenzothiophene (DBT) hydrodesulfurization (HDS) (at 5.59 MPa, T = 320 °C) was observed. Thus, monolayer Mo dispersion was assumed at that content. The aforementioned formulation was chosen to be promoted by Co at different concentrations, the maximum HDS activity being found for sulfided catalyst with Co/(Co + Mo) = 0.4. Nevertheless, the promotion observed by Co addition was small (by a factor of ∼3.2). The activity trends observed in the DBT HDS were well confirmed in the hydrotreatment of a real feedstock (straight-run gasoil). Dibenzothiophene reliably represented the behavior of organo-sulfur compounds present in the middle distillate, at the reaction conditions used in this study where sterically hindered compounds remained unreacted in the hydrotreated gasoil.
AB - Molybdenum (at 2.8, 3.3, 4.0 and 4.7 atoms nm-2) and cobalt (Co/(Co + Mo) ratios of 0.3, 0.4 and 0.5) were impregnated on wide-pore ZrO2-TiO2 mixed oxides (30-70) prepared with solvo-thermal treatment (80 °C, 1 day). Materials characterization comprised N2 physisorption, XRD, thermal analyses, and UV-vis DRS, Raman, and IR spectroscopies. For impregnated dried materials (non-calcined) at concentrations beyond 3.3 atom nm-2 and activated by sulfiding (H2S/H2, 400 °C) no further improvement in activity in dibenzothiophene (DBT) hydrodesulfurization (HDS) (at 5.59 MPa, T = 320 °C) was observed. Thus, monolayer Mo dispersion was assumed at that content. The aforementioned formulation was chosen to be promoted by Co at different concentrations, the maximum HDS activity being found for sulfided catalyst with Co/(Co + Mo) = 0.4. Nevertheless, the promotion observed by Co addition was small (by a factor of ∼3.2). The activity trends observed in the DBT HDS were well confirmed in the hydrotreatment of a real feedstock (straight-run gasoil). Dibenzothiophene reliably represented the behavior of organo-sulfur compounds present in the middle distillate, at the reaction conditions used in this study where sterically hindered compounds remained unreacted in the hydrotreated gasoil.
KW - CoMo catalyst
KW - Dibenzothiophene
KW - Hydrodesulfurization
KW - Straight-run gasoil
KW - ZrO-TiO
UR - http://www.scopus.com/inward/record.url?scp=41449105919&partnerID=8YFLogxK
U2 - 10.1016/j.cattod.2007.12.051
DO - 10.1016/j.cattod.2007.12.051
M3 - Artículo
SN - 0920-5861
VL - 133-135
SP - 282
EP - 291
JO - Catalysis Today
JF - Catalysis Today
IS - 1-4
ER -