Diels-Alder Reactions of Masked o-Benzoquinones: New Experimental Findings and a Theoretical Study of the Inverse Electron Demand Case

Odón Arjona, Rocío Medel, Joaquín Plumet, Rafael Herrera, Hugo A. Jiménez-Vázquez, Joaquín Tamariz

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10 Scopus citations

Abstract

Diels-Alder reactions of the masked o-benzoquinone (MOB) 2 with vinylene carbonate (3), the bicyclic derivatives 4, 5, and 6, and the intramolecular version of the 2-hydroxymethylfuran-MOB Diels-Alder reaction are described. In addition, a theoretical study of the Diels-Alder reactions of MOBs with enol and thioenol ethers is presented.

Original languageEnglish
Pages (from-to)2348-2354
Number of pages7
JournalJournal of Organic Chemistry
Volume69
Issue number7
DOIs
StatePublished - 2 Apr 2004

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