TY - JOUR
T1 - Crystal engineering
T2 - Supramolecular structures by cocrystallization of Meso-1,2-diphenyl-1,2-ethanediol and bisimines, simple cases of molecular recognition
AU - Reyes-Arellano, Alicia
AU - Boese, Roland
AU - Steller, Ingo
AU - Sustmann, Reiner
PY - 1995/12
Y1 - 1995/12
N2 - The crystal structures of molecular complexes between meso- 1,2-diphenyl-1,2-ethanediol and two bisimines (N,N′-(dibenzylidene)-ethylenediamine and glyoxylidene-bis(2,4-dimethyl-3-pentyl-amine) are reported at different temperatures. The structure-determining motif of the cocrystalline arrangement is one single O-H ⋯. N hydrogen bond resulting in infinite ladderlike polymers. The supramolecular structure is formed by recognition of fitting species: The d- or l-isomers do not arrange in such structures.1H NMR experiments show that no prearrangements take place by forming complexes in solution.
AB - The crystal structures of molecular complexes between meso- 1,2-diphenyl-1,2-ethanediol and two bisimines (N,N′-(dibenzylidene)-ethylenediamine and glyoxylidene-bis(2,4-dimethyl-3-pentyl-amine) are reported at different temperatures. The structure-determining motif of the cocrystalline arrangement is one single O-H ⋯. N hydrogen bond resulting in infinite ladderlike polymers. The supramolecular structure is formed by recognition of fitting species: The d- or l-isomers do not arrange in such structures.1H NMR experiments show that no prearrangements take place by forming complexes in solution.
KW - Molecular recognition
KW - crystal engineering
KW - supramolecular chemistry
UR - http://www.scopus.com/inward/record.url?scp=0000853918&partnerID=8YFLogxK
U2 - 10.1007/BF02310181
DO - 10.1007/BF02310181
M3 - Artículo
SN - 1040-0400
VL - 6
SP - 391
EP - 396
JO - Structural Chemistry
JF - Structural Chemistry
IS - 6
ER -