TY - JOUR
T1 - Controlling Li2CuO2 single phase transition to preserve cathode capacity and cyclability in Li-ion batteries
AU - Ramos-Sanchez, G.
AU - Romero-Ibarra, I. C.
AU - Vazquez-Arenas, J.
AU - Tapia, C.
AU - Aguilar-Eseiza, N.
AU - Gonzalez, I.
N1 - Publisher Copyright:
© 2017 Elsevier B.V.
PY - 2017/5/1
Y1 - 2017/5/1
N2 - Li2CuO2 is synthesized via a solid-state reaction and its structure and microstructure is characterized using X-Ray Diffraction, Scanning Electron Microscopy and N2 adsorption–desorption isotherms. The capacity of cathode material is evaluated at different preparation conditions to determine the factors affecting charge retention, cyclability, and assuring reproducibility during electrode fabrication. Progressing from previous reports, a maximum capacity retention of 140 mAh g− 1 is attained in the potential window from 1.5 to 4.2 V (Li/Li0) during ten cycles at C/15. The low capacity retention at extended cycling has been associated to the participation of irreversible oxygen redox process evaluated by theoretical calculations and cyclic voltammetry. These processes are minimized when the cycling potential window is confined from 2.0 to 3.8 V (Li/Li0), thus, achieving a higher capacity retention up to 100 mAh g− 1 during 60 cycles. Cycling at higher C/rates lowers the capacity down (60 mAh g− 1 at C/5), but the maximum capacity is restored when returning to C/15. Thus, making Li2CuO2 an attractive material either as active compound or additive in cathodes for Li-ion batteries, as a result of its intrinsic properties such as environmental benign, abundance, cost and straightforward preparation process.
AB - Li2CuO2 is synthesized via a solid-state reaction and its structure and microstructure is characterized using X-Ray Diffraction, Scanning Electron Microscopy and N2 adsorption–desorption isotherms. The capacity of cathode material is evaluated at different preparation conditions to determine the factors affecting charge retention, cyclability, and assuring reproducibility during electrode fabrication. Progressing from previous reports, a maximum capacity retention of 140 mAh g− 1 is attained in the potential window from 1.5 to 4.2 V (Li/Li0) during ten cycles at C/15. The low capacity retention at extended cycling has been associated to the participation of irreversible oxygen redox process evaluated by theoretical calculations and cyclic voltammetry. These processes are minimized when the cycling potential window is confined from 2.0 to 3.8 V (Li/Li0), thus, achieving a higher capacity retention up to 100 mAh g− 1 during 60 cycles. Cycling at higher C/rates lowers the capacity down (60 mAh g− 1 at C/5), but the maximum capacity is restored when returning to C/15. Thus, making Li2CuO2 an attractive material either as active compound or additive in cathodes for Li-ion batteries, as a result of its intrinsic properties such as environmental benign, abundance, cost and straightforward preparation process.
KW - C-rates
KW - Cyclability
KW - Electrode preparation
KW - Li-ion batteries
KW - LiCuO cathode
UR - http://www.scopus.com/inward/record.url?scp=85013973592&partnerID=8YFLogxK
U2 - 10.1016/j.ssi.2017.02.018
DO - 10.1016/j.ssi.2017.02.018
M3 - Artículo
AN - SCOPUS:85013973592
SN - 0167-2738
VL - 303
SP - 89
EP - 96
JO - Solid State Ionics
JF - Solid State Ionics
ER -