Condensed cyclic and bridged-ring systems. Part 15. Acid-catalysed intramolecular alkylations in 1-diazoacetyl-1,2,3,4-tetrahydro-9-methoxy- 1methylphenanthrenes

Sitaram Pal, Bimal K. Banik, Usha Ranjan Ghatak

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

The acid-catalysed reaction of the 1 -diazoacetyltetrahydrophenanthrene 1a and the three new related diazoketones Ib-d gave, in addition to the respective bridged ketones 2a-d and the pentaleno annelated ketones 3a-d, the acephenanthrones 4a-d, which were also prepared in excellent yield by the rhodium(II) acetate-induced reaction of the diazoketones.

Original languageEnglish
Pages (from-to)1105-1110
Number of pages6
JournalJournal of the Chemical Society, Perkin Transactions 1
Issue number8
DOIs
StatePublished - 1994
Externally publishedYes

Fingerprint

Dive into the research topics of 'Condensed cyclic and bridged-ring systems. Part 15. Acid-catalysed intramolecular alkylations in 1-diazoacetyl-1,2,3,4-tetrahydro-9-methoxy- 1methylphenanthrenes'. Together they form a unique fingerprint.

Cite this