Brownian dynamics simulations of Laponite colloid suspensions

Colloidal suspensions of Laponite clay platelets are studied by means of Brownian dynamics simulations. The platelets carry discrete charged sites which interact via a Yukawa potential. As in the paper by S. Kutter [J. Chem. Phys. 112, 311 (2000)], two models are considered. In the first one all surface sites are identically negative charged, whereas in the second one, rim charges of opposite sign are included. These models mimic the behavior of the Laponite particles in different media. They are employed in a series of simulations for different Laponite concentrations and for two values of the Debye length. For the equilibrium states, the system structure is studied by center-to-center and orientational pair distribution functions. Long-time translational and rotational self-diffusion coefficients are computed by two different methods, which yield very similar results.