Behaviour of Prussian Blue during its interaction with ozone

E. Reguera; J. Fernández-Bertrán; C. Díaz; J. Molerio

doi:10.1007/BF02418603

Behaviour of Prussian Blue during its interaction with ozone

E. Reguera, J. Fernández-Bertrán, C. Díaz, J. Molerio

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Abstract

The interaction of ozone with Prussian Blue has been studied by Mössbauer, infrared and XRD techniques. All spectral results reveal a reversible conversion of ferrocyanide to ferricyanide with preservation of the crystal skeleton. Ferric ferricyanide obtained by ozonization of ferric ferrocyanide has Mössbauer parameters different to those of an ordered Prussian Brown, which has been attributed to secondary reaction products located at the zeolite voids of the former compound.

Original language	English
Pages (from-to)	285-294
Number of pages	10
Journal	Hyperfine Interactions
Volume	73
Issue number	3-4
DOIs	https://doi.org/10.1007/BF02418603
State	Published - Oct 1992
Externally published	Yes

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title = "Behaviour of Prussian Blue during its interaction with ozone",

abstract = "The interaction of ozone with Prussian Blue has been studied by M{\"o}ssbauer, infrared and XRD techniques. All spectral results reveal a reversible conversion of ferrocyanide to ferricyanide with preservation of the crystal skeleton. Ferric ferricyanide obtained by ozonization of ferric ferrocyanide has M{\"o}ssbauer parameters different to those of an ordered Prussian Brown, which has been attributed to secondary reaction products located at the zeolite voids of the former compound.",

author = "E. Reguera and J. Fern{\'a}ndez-Bertr{\'a}n and C. D{\'i}az and J. Molerio",

year = "1992",

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T1 - Behaviour of Prussian Blue during its interaction with ozone

AU - Reguera, E.

AU - Fernández-Bertrán, J.

AU - Díaz, C.

AU - Molerio, J.

PY - 1992/10

Y1 - 1992/10

N2 - The interaction of ozone with Prussian Blue has been studied by Mössbauer, infrared and XRD techniques. All spectral results reveal a reversible conversion of ferrocyanide to ferricyanide with preservation of the crystal skeleton. Ferric ferricyanide obtained by ozonization of ferric ferrocyanide has Mössbauer parameters different to those of an ordered Prussian Brown, which has been attributed to secondary reaction products located at the zeolite voids of the former compound.

AB - The interaction of ozone with Prussian Blue has been studied by Mössbauer, infrared and XRD techniques. All spectral results reveal a reversible conversion of ferrocyanide to ferricyanide with preservation of the crystal skeleton. Ferric ferricyanide obtained by ozonization of ferric ferrocyanide has Mössbauer parameters different to those of an ordered Prussian Brown, which has been attributed to secondary reaction products located at the zeolite voids of the former compound.

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U2 - 10.1007/BF02418603

DO - 10.1007/BF02418603

M3 - Artículo

SN - 0304-3834

VL - 73

SP - 285

EP - 294

JO - Hyperfine Interactions

JF - Hyperfine Interactions

IS - 3-4

ER -

Behaviour of Prussian Blue during its interaction with ozone

Abstract

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