TY - JOUR
T1 - Authentication of concentrated orange essential oils using photoacoustic spectroscopy
AU - López Muñoz, G. A.
AU - Balderas López, J. A.
AU - López González, R. F.
N1 - Funding Information:
Acknowledgments The authors acknowledge Zaber Technologies Inc. for providing a micro-linear actuator for this study. We acknowledge Química Aromática S.A., COFAA-IPN and CONACyT for financial support.
PY - 2012
Y1 - 2012
N2 - Photoacoustic spectroscopy (PS) was used to study the thermal diffusivity and its relation with the composition in folded (concentrated) cold-pressed Mexican orange essential oils. A linear relation between the amplitude (on a semi-log scale) and phase, as functions of the sample thickness, for PS was obtained through a theoretical model to fit the experimental data for thermal-diffusivity measurements in concentrated orange essential oils. Experimental results showed a linear increase in thermal-diffusivity values with the folding degree: 5-fold, 10-fold, 20-fold, and 35-fold due to a decrease in terpenes (mainly D-limonene) related with the folding process that can be correlated with the thermal diffusivity of the orange essential oils. The obtained values in this study and those previously reported (see Int. J. Thermophys. 32, 1066, 2011) showed the possibility of using this thermal property to make distinctions between citrus oils obtained by different extraction processes and also between concentrated citrus oils. This provides the viability of a new complementary method for this purpose, contrasting with the use of density and refraction index, physical properties commonly used in the authentication of citrus essential oils.
AB - Photoacoustic spectroscopy (PS) was used to study the thermal diffusivity and its relation with the composition in folded (concentrated) cold-pressed Mexican orange essential oils. A linear relation between the amplitude (on a semi-log scale) and phase, as functions of the sample thickness, for PS was obtained through a theoretical model to fit the experimental data for thermal-diffusivity measurements in concentrated orange essential oils. Experimental results showed a linear increase in thermal-diffusivity values with the folding degree: 5-fold, 10-fold, 20-fold, and 35-fold due to a decrease in terpenes (mainly D-limonene) related with the folding process that can be correlated with the thermal diffusivity of the orange essential oils. The obtained values in this study and those previously reported (see Int. J. Thermophys. 32, 1066, 2011) showed the possibility of using this thermal property to make distinctions between citrus oils obtained by different extraction processes and also between concentrated citrus oils. This provides the viability of a new complementary method for this purpose, contrasting with the use of density and refraction index, physical properties commonly used in the authentication of citrus essential oils.
KW - Oil authentication
KW - Orange oil
KW - Photoacoustic spectroscopy
KW - Terpene content
KW - Thermal diffusivity
UR - http://www.scopus.com/inward/record.url?scp=84888312817&partnerID=8YFLogxK
U2 - 10.1007/s10765-012-1263-4
DO - 10.1007/s10765-012-1263-4
M3 - Artículo
AN - SCOPUS:84888312817
SN - 0195-928X
VL - 33
SP - 1834
EP - 1841
JO - International Journal of Thermophysics
JF - International Journal of Thermophysics
IS - 10-11
ER -