TY - JOUR
T1 - A new route for the synthesis of methylene dibenzoate by using an ionic liquid
AU - Likhanova, Natalya V.
AU - Lijanova, Irina V.
AU - Alvarado, Laura P.Morelos
AU - García, Marcos Martínez
AU - Hernández-Ortega, Simón
AU - Xometl, Octavio Olivares
PY - 2013
Y1 - 2013
N2 - Ionic liquids are often used together with dichloromethane in different reactions. This combination can be problematic because the use of ionic liquids with a carboxylic acid as an anion and dichloromethane can lead to the formation of methylene diesters. The reaction of trioctylmethylammonium benzoate with dichloromethane was studied, where the ionic liquid acted as reactant, solvent and catalyst. The molecular structure of methylene dibenzoate was determined by X-ray crystallography.
AB - Ionic liquids are often used together with dichloromethane in different reactions. This combination can be problematic because the use of ionic liquids with a carboxylic acid as an anion and dichloromethane can lead to the formation of methylene diesters. The reaction of trioctylmethylammonium benzoate with dichloromethane was studied, where the ionic liquid acted as reactant, solvent and catalyst. The molecular structure of methylene dibenzoate was determined by X-ray crystallography.
KW - Dichloromethane
KW - Ionic liquids
KW - Metilenedibenzoates
KW - Synthesis
UR - http://www.scopus.com/inward/record.url?scp=84874837722&partnerID=8YFLogxK
U2 - 10.2174/138527213805289178
DO - 10.2174/138527213805289178
M3 - Artículo
SN - 1385-2728
VL - 17
SP - 79
EP - 82
JO - Current Organic Chemistry
JF - Current Organic Chemistry
IS - 1
ER -