TY - JOUR
T1 - [2-(Diphenylphosphanyl)benzenethiolato-κ2P,S] (pyridine-2-thiolato-κS)(triphenylphosphine-κP)palladium(II)
AU - Ríos-Sanchez, Raúl
AU - Hernández-Ortega, Simón
AU - Morales-Morales, David
AU - Avila-Sorrosa, Alcives
PY - 2010/9
Y1 - 2010/9
N2 - In the title compound, [Pd(C5H4NS)(C 18H14PS)(C18H15P)], the Pd II atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenylphosphanyl) benzenethiolate ligand and the other two by a P atom from a triphenylphosphine ligand and an S atom from a pyridine-2-thiolate ligand, exhibiting a trans arrangement of the two P-donor atoms. In the crystal structure, weak intra- and intermolecular C-H⋯π and π-π interactions are observed. The pyridyl ring is equally disordered over two positions.
AB - In the title compound, [Pd(C5H4NS)(C 18H14PS)(C18H15P)], the Pd II atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenylphosphanyl) benzenethiolate ligand and the other two by a P atom from a triphenylphosphine ligand and an S atom from a pyridine-2-thiolate ligand, exhibiting a trans arrangement of the two P-donor atoms. In the crystal structure, weak intra- and intermolecular C-H⋯π and π-π interactions are observed. The pyridyl ring is equally disordered over two positions.
UR - http://www.scopus.com/inward/record.url?scp=77956316931&partnerID=8YFLogxK
U2 - 10.1107/S160053681003357X
DO - 10.1107/S160053681003357X
M3 - Artículo
C2 - 21588560
SN - 1600-5368
VL - 66
SP - m1170-m1171
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 9
ER -